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140066

1,3,5-三溴苯

98%

别名:

1,3,5-三溴苯

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关于此项目

经验公式（希尔记法）:
C6H3Br3
化学文摘社编号:
626-39-1
分子量:
314.80
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24848449
EC Number:
210-947-3
Beilstein/REAXYS Number:
1858917
MDL number:
MFCD00000080
Assay:
98%
Form:
powder
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Quality Level

100

assay

98%

form

powder

bp

271 °C (lit.)

mp

117-121 °C (lit.)

functional group

bromo

SMILES string

Brc1cc(Br)cc(Br)c1

InChI

1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H

InChI key

YWDUZLFWHVQCHY-UHFFFAOYSA-N

General description

  • 1,3,5-三溴苯（TBB）作为衍生化步骤的内标，用于通过气相色谱-质谱法测定人血浆和尿液中的氰化物。
  • TBB与[60]-和[70]富勒烯反应形成化学计量为1：2的分子复合物。
  • TBB在 Pd(Ph3)4 催化剂存在下，与全氟链烯基锌试剂反应，得到新型三官能团单体1,3,5-三(α, β, β-三氟乙烯基)苯。

hcodes

H413

Hazard Classifications

Aquatic Chronic 4

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB3917
STBK8122
STBJ5368
STBG9695
STBF9845V

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Lawrence A Ford et al.
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
S Kage et al.
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.
Kakali Datta et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 66-70 (2005-11-01)
By UV-vis spectrophotometric method it has been shown that 1,3,5-tribromobenzene (TBB) forms molecular complexes of 1:2 stoichiometry with [60]- and [70]fullerenes. An isosbestic point could be detected in case of the [70]fullerene complex. The formation constant of the [60]fullerene complex
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全球贸易项目编号

货号GTIN
140066-100G04061838733146
140066-25G04061838733153