140414
3,5-二叔丁基-2-羟基苯甲醛
99%
别名:
3,5-二叔丁基水杨醛
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选择尺寸
关于此项目
线性分子式:
HOC6H2[C(CH3)3]2CHO
化学文摘社编号:
分子量:
234.33
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
表单
powder or crystals
mp
59-61 °C (lit.)
官能团
aldehyde
SMILES字符串
CC(C)(C)c1cc(C=O)c(O)c(c1)C(C)(C)C
InChI
1S/C15H22O2/c1-14(2,3)11-7-10(9-16)13(17)12(8-11)15(4,5)6/h7-9,17H,1-6H3
InChI key
RRIQVLZDOZPJTH-UHFFFAOYSA-N
一般描述
3，5-二叔丁基-2-羟基苯甲醛与
- 2- {N-（2′-氨基乙烷）} -氨基-1-环戊二硫代羧酸甲酯进行缩合反应，得到席夫碱配体
- 水杨醛亚胺铜（II）和钴（II）配合物合成过程中的 N，N-二乙基-2-甲基-1，4-苯二胺
应用
3,5-二叔丁基-2-羟基苯甲醛用于合成
- Mn（III）-salen 络合物及其二氨基前体 5，6-二氨基-5，6-二脱氧-1，2-O-异亚丙基-3-O-甲基-β-L-呋喃核糖
- 用于对映选择性铜催化将苯乙炔加成到亚胺的手性席夫碱配体
- 用于对二选择性地将二乙基锌加成到醛的手性恶唑烷配体
- 锡席夫碱与组氨酸类似物的复合物
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Ariadna Garza-Ortiz et al.
Bioinorganic chemistry and applications, 2013, 502713-502713 (2013-07-19)
Five novel tin Schiff base complexes with histidine analogues (derived from the condensation reaction between L-histidine and 3,5-di-tert-butyl-2-hydroxybenzaldehyde) have been synthesized and characterized. Characterization has been completed by IR and high-resolution mass spectroscopy, 1D and 2D solution NMR ((1)H, (13)C and
Mild and efficient synthesis of 5, 6-diamino-5, 6-dideoxy-1, 2-O-isopropylidene-3- O -methyl-?-l-idofuranose: precursor of the first carbohydrate-derived chiral Mn (III)-salen complex.
Yan S and Klemm D.
Tetrahedron, 58(50), 10065-10071 (2002)
Tetrahedron Asymmetry, 18, 1124-1124 (2007)
Co (II) and Cu (II) Schiff base complexes of bis (N-(4-diethylamino-2-methylphenyl)-3, 5-di-tert-butylsalicylaldimine): Electrochemical and X-ray structural study.
Ulusoy M, et al.
Structural Chemistry, 19(5), 749-755 (2008)
Saeid Menati et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1033-1040 (2012-08-29)
A novel Schiff base (H(2)cddi(t)butsalen) ligand was prepared via condensation of Methyl-2-{N-(2'-aminoethane)}-amino-1-cyclopentenedithiocarboxylate(Hcden) and 3,5-di-tert-butyl-2-hydroxybenzaldehyde. The ligand and Ni(II) and Cu(II) complexes were characterized based on elemental analysis, IR, (1)H NMR, (13)C NMR, UV-Vis spectrometry and cyclic voltammetry. The structure of
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