143995
炔丙氯
98%
别名:
3-氯丙炔
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线性分子式:
HC≡CCH2Cl
化学文摘社编号:
分子量:
74.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-856-9
Beilstein/REAXYS Number:
506005
MDL number:
产品名称
炔丙氯, 98%
SMILES string
ClCC#C
InChI key
LJZPPWWHKPGCHS-UHFFFAOYSA-N
InChI
1S/C3H3Cl/c1-2-3-4/h1H,3H2
assay
98%
form
liquid
refractive index
n20/D 1.435 (lit.)
bp
58 °C (lit.)
solubility
benzene: miscible
chloroform: miscible
diethyl ether: miscible
ethanol: miscible
ethyl acetate: miscible
ethylene glycol: miscible
water: insoluble
density
1.03 g/mL at 25 °C (lit.)
functional group
alkyl halide
chloro
storage temp.
2-8°C
Quality Level
Application
炔丙氯已用于在199 nm下研究光激发时解离的炔丙氯的发射光谱。它已用于合成双酚A的新型四芳基类似物和双酚A炔丙基树脂的三芳基类似物。
General description
炔丙氯是一种有效的炔丙基化剂。它可通过脉冲激光光解生成炔丙基。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
66.2 °F - closed cup
flash_point_c
19 °C - closed cup
ppe
Faceshields, Gloves, Goggles
法规信息
危险化学品
此项目有
Akira Matsugi et al.
The journal of physical chemistry. A, 115(26), 7610-7624 (2011-05-24)
The kinetics and mechanisms of the self-reaction of allyl radicals and the cross-reaction between allyl and propargyl radicals were studied both experimentally and theoretically. The experiments were carried out over the temperature range 295-800 K and the pressure range 20-200
Investigating the C-Cl Antibonding Character in the pp* Excited State of Vinyl, Allyl, and Propargyl Chloride: Emission Spectra and ab Initio Calculations.
Browning PW, et al.
The Journal of Physical Chemistry, 100(19), 7765-7771 (1996)
DIPROPARGYL ETHERS OF HIGH ASPECT RATIO BISPHENOLS.
Filipova TS, et al.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 48(1), 388-388 (2007)
Lyudmila A Grischenko et al.
Carbohydrate research, 376, 7-14 (2013-06-04)
New arabinogalactan propargyl ethers with degree of substitution (DS) up to 2.8 have been obtained by propargylation of arabino-3,6-galactan (AG) with propargyl bromide (PB) in the two-phase system 30-60% КОН aqueous solution/toluene in the presence of triethylbenzylammonium chloride (TEBAС) or
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