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关于此项目
线性分子式:
C2H5O2CCH2S(CH3)2Br
化学文摘社编号:
分子量:
231.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-968-3
MDL number:
Assay:
97%
Form:
solid
InChI key
JXFPTJYKYKVENJ-UHFFFAOYSA-M
InChI
1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1
SMILES string
Br.CCOC(=O)C[S](C)C
assay
97%
form
solid
mp
90-94 °C (lit.)
functional group
ester, thioether
Quality Level
Application
(Ethoxycarbonylmethyl)dimethylsulfonium bromide was used in synthesis of α-sulfanyl-β-amino acid derivatives by using nanocrystalline magnesium oxide. It was used during cyclopropanation of (-)-(S)-2-(p-tolylsulfinyl)cyclopent-2-enone.
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
signalword
Warning
hcodes
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Synthesis of a-sulfanyl-?-amino acid derivatives by using nanocrystalline magnesium oxide.
Kantam ML, et al.
Tetrahedron, 66(27), 5042-5052 (2010)
Constrained cycloalkyl analogues of glutamic acid: stereocontrolled synthesis of (+)-2-aminobicyclo [3.1. 0] hexane-2, 6-dicarboxylic acid (LY354740) and its 6-phosphonic acid analogue
Krysiak J, et al.
Tetrahedron Asymmetry, 21(11), 1486-1493 (2010)
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