产品名称
苄基三甲基溴化铵, 97%
方案
97%
表单
solid
mp
230-232 °C (lit.)
SMILES字符串
[Br-].C[N+](C)(C)Cc1ccccc1
InChI
1S/C10H16N.BrH/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H/q+1;/p-1
InChI key
UUZYBYIOAZTMGC-UHFFFAOYSA-M
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应用
苄基三甲基溴化铵 (BTMAB) 可作为起始材料，与CrO3和HF水溶液反应合成苄基三甲基氟铬酸铵 (BTMAFC)。BTMAFC可作为高效氧化剂，将肟选择性氧化为酮或醛，以及将一级和二级醇、烯丙醇和苯甲醇氧化成它们相应的羰基化合物形式。
BTMAB还可用作：
BTMAB还可用作：
- 氧化剂，在DMSO的存在下将单取代苄胺氧化成对应的醛亚胺。
- 在镍催化剂的作用下，作为苄基化试剂将芳基酰胺C-H键苯甲酰化。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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Indian Journal of Chemistry, 41A, 541-546 (2002)
Nickel-Catalyzed Benzylation of C- H Bonds in Aromatic Amides with Benzyltrimethylammonium Halides
Sasagawa A, et al.
Israel Journal of Chemistry, 57(10-11), 964-967 (2017)
Benzyltrimethylammonium fluorochromate (VI): a novel, efficient and selective oxidant
Kassaee MZ, et al.
Acta Chimica Slovenica, 51, 743-750 (2004)
Weisheng Lin et al.
Analytica chimica acta, 583(1), 98-102 (2007-03-28)
The importance of benzyltriethyl ammonium chloride (BTEAC) in industrial applications has stimulated the development of a number of methods for its determination. In this paper, a high performance capillary electrophoresis (CE) method, coupled with an extraction technique for determining BTEAC
Purushothaman Gopinath et al.
The Journal of organic chemistry, 74(16), 6291-6294 (2009-07-22)
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
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