产品名称
苄基三甲基溴化铵, 97%
质量水平
方案
97%
表单
solid
mp
230-232 °C (lit.)
SMILES字符串
[Br-].C[N+](C)(C)Cc1ccccc1
InChI
1S/C10H16N.BrH/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H/q+1;/p-1
InChI key
UUZYBYIOAZTMGC-UHFFFAOYSA-M
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应用
苄基三甲基溴化铵 (BTMAB) 可作为起始材料，与CrO3和HF水溶液反应合成苄基三甲基氟铬酸铵 (BTMAFC)。BTMAFC可作为高效氧化剂，将肟选择性氧化为酮或醛，以及将一级和二级醇、烯丙醇和苯甲醇氧化成它们相应的羰基化合物形式。
BTMAB还可用作：
BTMAB还可用作：
- 氧化剂，在DMSO的存在下将单取代苄胺氧化成对应的醛亚胺。
- 在镍催化剂的作用下，作为苄基化试剂将芳基酰胺C-H键苯甲酰化。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Nickel-Catalyzed Benzylation of C- H Bonds in Aromatic Amides with Benzyltrimethylammonium Halides
Sasagawa A, et al.
Israel Journal of Chemistry, 57(10-11), 964-967 (2017)
Benzyltrimethylammonium fluorochromate (VI): a novel, efficient and selective oxidant
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Acta Chimica Slovenica, 51, 743-750 (2004)
Benzyltrimethylammonium fluorochromate (VI): a novel, efficient and selective oxidant
Rekha S and Seema K
Indian Journal of Chemistry, 41A, 541-546 (2002)
Herman Odens et al.
Chemical & pharmaceutical bulletin, 62(9), 933-936 (2014-09-02)
Fatty acid synthase (FASN) is the enzyme that synthesizes fatty acids de novo in human cells. Although FASN is generally expressed at low levels in most normal tissues, its expression is highly upregulated in many cancers. Consistent with this notion
Lena Edström et al.
Journal of chromatography. A, 1218(15), 1966-1973 (2010-10-05)
It has recently been demonstrated, using mathematical models, how peculiar overloaded band profiles of basic compounds are due to the local pH in the column when using low capacity buffers. In this study, overloaded peak shapes resulting after injection of
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