147532
1,3,5-苯三甲酰氯
98%
别名:
1,3,5-均三苯甲酰氯, 1,3,5-苯三酰三氯, 均苯三甲酰氯
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关于此项目
线性分子式:
C6H3(COCl)3
化学文摘社编号:
分子量:
265.48
UNSPSC Code:
12352100
NACRES:
NA.23
PubChem Substance ID:
EC Number:
224-594-8
Beilstein/REAXYS Number:
2940936
MDL number:
InChI key
UWCPYKQBIPYOLX-UHFFFAOYSA-N
InChI
1S/C9H3Cl3O3/c10-7(13)4-1-5(8(11)14)3-6(2-4)9(12)15/h1-3H
SMILES string
ClC(=O)c1cc(cc(c1)C(Cl)=O)C(Cl)=O
assay
98%
form
solid
bp
180 °C/16 mmHg (lit.)
mp
32-38 °C (lit.)
solubility
chloroform: soluble 10%, clear to very slightly hazy, colorless to faintly yellow
density
1.487 g/mL at 25 °C (lit.)
Quality Level
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General description
1，3，5-苯三甲酰氯与炔丙醇反应生成三丙基-2-炔基苯-1，3，5-三羧酸酯。
Application
1，3，5-苯三甲酰氯用于合成手性偶氮芳族树枝状聚合物体系。用它来研究含有机磷萃取剂作为载体的活化复合膜的结构。它是从 3-和 4-甲基氨基吡啶合成的两种三元酰胺的起始原料，其在用硝酸钯（II） DMSO 溶液处理时自组装成纳米球。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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The Journal of organic chemistry, 71(22), 8412-8416 (2006-10-27)
The design and self-assembly of two new flexible supramolecular nanoballs are described. These assemblies incorporate two flexible tritopic amide and ester building blocks and were prepared in excellent yields (96-97%) via coordination driven self-assembly. The first resulted from the reaction
Luigi Angiolini et al.
Chirality, 22(1), 99-109 (2009-04-24)
New chiral azoaromatic dendrimeric systems have been synthesized starting from 1,3,5-benzenetricarbonyl trichloride as the core molecule. The simultaneous presence of the (S)-3-hydroxy pyrrolidinyl ring as the optically active moiety and the azobenzene donor-acceptor conjugated system as the photochromic group with
Behnam Khorshidi et al.
Scientific reports, 8(1), 784-784 (2018-01-18)
The development of nano-enabled composite materials has led to a paradigm shift in the manufacture of high-performance nanocomposite membranes with enhanced permeation, thermo-mechanical, and antibacterial properties. The major challenges to the successful incorporation of nanoparticles (NPs) to polymer films are
Zhe Yang et al.
Environmental science & technology, 52(16), 9341-9349 (2018-07-26)
Conventional thin-film composite (TFC) membranes suffer from the trade-off relationship between permeability and selectivity, known as the "upper bound". In this work, we report a high performance thin-film composite membrane prepared on a tannic acid (TA)-Fe nanoscaffold (TFCn) to overcome
Kranthikumar Tungala et al.
Carbohydrate polymers, 95(1), 295-298 (2013-04-27)
Triprop-2-ynyl benzene-1,3,5-tricarboxylate (A) is synthesized by the reaction of 1,3,5-benzenetricarbonyl trichloride with propargyl alcohol and (A) is clicked with mono-6-deoxy-6-azido-β-cyclodextrin (N3-β-CD) in the presence of copper(I) bromide catalyst. N3-β-CD has been prepared from β-cyclodextrin (β-CD) on treatment with toluenesulfonyl chloride
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