147834
Michler 酮
98%
别名:
4,4′-双(二甲氨基)二苯甲酮
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关于此项目
线性分子式:
[(CH3)2NC6H4]2CO
化学文摘社编号:
分子量:
268.35
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
202-027-5
Beilstein/REAXYS Number:
790733
MDL number:
InChI key
VVBLNCFGVYUYGU-UHFFFAOYSA-N
InChI
1S/C17H20N2O/c1-18(2)15-9-5-13(6-10-15)17(20)14-7-11-16(12-8-14)19(3)4/h5-12H,1-4H3
SMILES string
CN(C)c1ccc(cc1)C(=O)c2ccc(cc2)N(C)C
assay
98%
form
powder
mp
174-176 °C (lit.)
Quality Level
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General description
米氏′酮（MK）是一种二苯甲酮衍生物，能够发射温度依赖型磷光。它在较低温度下具有三重态-三重态吸收光谱。
Application
MK可用作添加剂，在染料制备中充当光引发剂。它也可用作合成4,4′-双{N,N,二甲基, N (2-乙氧羰基l-1-丙烯基) 六氟锑酸铵}二苯甲酮 (MKEA) 的前体材料。
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
New Push-Pull Dyes Derived from Michler?s Ketone For Polymerization Reactions Upon Visible Lights.
Tehfe M, et al.
Macromolecules, 46(10), 3761-3770 (2013)
Michler's ketone.
Report on carcinogens : carcinogen profiles, 12, 270-271 (2011-08-24)
Excited state dynamics of Michler's ketone: a laser flash photolysis study
Singh AK, et al.
Research on Chemical Intermediates, 27(1-2), 125-136 (2001)
Synthesis of a novel addition-fragmentation agent based on Michler's ketone and its use as photo-initiator for cationic polymerization
Onen A and Yagci Y
Polymer, 42(16), 6681-6685 (2001)
Cinzia Chiappe et al.
The journal of physical chemistry. A, 110(14), 4937-4941 (2006-04-08)
Michler's ketone (MK) and tetracyanoethene (TCNE) may be used as a UV-vis probe to investigate the solvent properties of ionic liquids (ILs). In molecular solvents, MK and TCNE give an electron donor-acceptor (EDA) complex, a zwitterionic species or a radical
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