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Merck
CN

147982

(S)-(+)-2-辛醇

99%

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线性分子式:
CH3(CH2)5CH(OH)CH3
化学文摘社编号:
分子量:
130.23
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-213-6
Beilstein/REAXYS Number:
1719323
MDL number:
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产品名称

(S)-(+)-2-辛醇, 99%

InChI key

SJWFXCIHNDVPSH-QMMMGPOBSA-N

InChI

1S/C8H18O/c1-3-4-5-6-7-8(2)9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

SMILES string

CCCCCC[C@H](C)O

assay

99%

form

liquid

optical activity

[α]20/D +9.5°, neat

optical purity

ee: 98% (GLC)

refractive index

n20/D 1.426 (lit.)

bp

175 °C (lit.)

density

0.822 g/mL at 25 °C (lit.)

Quality Level

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Application

(S)-(+)-2-辛醇可被用于:
  • 制备5-苄氧基异邻苯二甲酸衍生物溶液,其可被用作包含有热解石墨的2D手性自组装系统。
  • 作为手性模板用于研究对映选择性乙二醇酯化。
  • 作为起始材料用于制备(+)-(S)-2-甲苯磺酸辛酯,一种可用于制备(−)-(R)-2-卤代和叠氮辛烷的中间体。

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Convenient preparation of optically active 2-halooctanes and related compounds
San Filippo Jr J and Romano LJ
The Journal of Organic Chemistry, 40(10), 1514-1515 (1975)
Development of simulation approach for two-dimensional chiral molecular self-assembly driven by hydrogen bond at the liquid/solid interface
Qin Y, et al.
Surface Science, 663, 71-80 (2017)
Effect of imprinting sol-gel immobilized lipase with chiral template substrates in esterification of (R)-(+)-and (S)-(-)-glycidol.
Furukawa S, et al.
Journal of Molecular Catalysis. B, Enzymatic, 17(1), 23-28 (2002)
Paul Masset et al.
Cell, 182(1), 112-126 (2020-06-07)
Every decision we make is accompanied by a sense of confidence about its likely outcome. This sense informs subsequent behavior, such as investing more-whether time, effort, or money-when reward is more certain. A neural representation of confidence should originate from
Anindya S Bhattacharjee et al.
Cell reports, 28(11), 2966-2978 (2019-09-12)
The olfactory environment is first represented by glomerular activity patterns in the olfactory bulb. It remains unclear how these representations intersect with sampling behavior to account for the time required to discriminate odors. Using different chemical classes, we investigate glomerular

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