Merck
CN
所有图片(2)

文件

148083

Sigma-Aldrich

1,1,1-三(羟甲基)丙烷

97%

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别名:
2-乙基-2-羟甲基-1,3-丙二醇, 三羟甲基丙烷
线性分子式:
CH3CH2C(CH2OH)3
CAS号:
77-99-6
分子量:
134.17
Beilstein:
1698309
EC 号:
201-074-9
MDL编号:
MFCD00004694
PubChem化学物质编号:
24848880
NACRES:
NA.22

蒸汽密度

4.8 (vs air)

蒸汽压

<1 mmHg ( 20 °C)

检测方案

97%

形式

(Powder or Crystals or Granules or Chunks)

自燃温度

1301 °F

bp

159-161 °C/2 mmHg (lit.)

mp

56-58 °C (lit.)

SMILES string

CCC(CO)(CO)CO

InChI

1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3

InChI key

ZJCCRDAZUWHFQH-UHFFFAOYSA-N

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相关类别

应用

1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.

象形图

Health hazard
GHS08

警示用语：

Warning

危险声明

H361fd

危险分类

Repr. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

356.0 °F - Cleveland open cup

闪点(°C)

180 °C - Cleveland open cup

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Daniel Cohn et al.
Biomaterials, 25(27), 5875-5884 (2004-06-03)
This article introduces novel biocompatible tissue adhesives that do not involve any chemical or biochemical reactions, during their application in vivo. The use of these new adhesives is based exclusively on their temperature-dependent rheological properties. Since biocompatibility and biodegradability are
Y Y Linko et al.
Journal of biotechnology, 66(1), 41-50 (1998-12-29)
The interest in the applications of biocatalysis in organic syntheses has rapidly increased. In this context, lipases have recently become one of the most studied groups of enzymes. We have demonstrated that lipases can be used as biocatalyst in the
Stephanie E A Gratton et al.
Journal of controlled release : official journal of the Controlled Release Society, 121(1-2), 10-18 (2007-07-24)
A novel method for the fabrication of polymeric particles on the order of tens of nanometers to several microns is described. This imprint lithographic technique called PRINT (Particle Replication In Non-wetting Templates), takes advantage of the unique properties of elastomeric
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