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线性分子式:
CH3CH2C(CH2OH)3
化学文摘社编号:
分子量:
134.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-074-9
Beilstein/REAXYS Number:
1698309
MDL number:
Assay:
97%
Form:
(Powder or Crystals or Granules or Chunks)
产品名称
1,1,1-三(羟甲基)丙烷, 97%
InChI key
ZJCCRDAZUWHFQH-UHFFFAOYSA-N
InChI
1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3
SMILES string
CCC(CO)(CO)CO
vapor density
4.8 (vs air)
vapor pressure
<1 mmHg ( 20 °C)
assay
97%
form
(Powder or Crystals or Granules or Chunks)
autoignition temp.
1301 °F
bp
159-161 °C/2 mmHg (lit.)
mp
56-58 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.
signalword
Warning
hcodes
Hazard Classifications
Repr. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
356.0 °F - Cleveland open cup
flash_point_c
180 °C - Cleveland open cup
ppe
Eyeshields, Gloves, type N95 (US)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
M A Wright et al.
Applied and environmental microbiology, 59(4), 1072-1076 (1993-04-01)
A bacterium that was able to utilize Emkarate 1550 (E1550), a synthetic lubricant ester, as the sole source of carbon was isolated. The isolate was tentatively identified as Micrococcus roseus. The components of the E1550 ester, octanoate, decanoate, and 1,1,1-tris(hydroxymethyl)propane
Ruzaimah Nik Mohamad Kamil et al.
Bioresource technology, 101(15), 5877-5884 (2010-03-23)
A mathematical model describing chemical kinetics of transesterification of palm-based methyl esters with trimethylolpropane has been developed. The model was developed by utilizing nonlinear regression method, which is an efficient and powerful way to determine rate constants for both forward
Vita Kiriliauskaitė et al.
Journal of industrial microbiology & biotechnology, 38(9), 1561-1566 (2011-02-18)
The ability of the commercial lipolytic enzyme Lipoprime 50T to catalyze the biotechnologically important synthesis of the biodegradable and environmentally acceptable trimethylolpropane (2-ethyl-2-(hydroxymethyl)-1,3-propanediol) ester of oleic acid was investigated. Simple and accurate thin-layer chromatography and computer analysis methods were used
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