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148482

二苯基硅烷

Name: 二苯基硅烷
Brand: ALDRICH

97%

别名:

Diphenyl silane, Diphenylsilicon

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关于此项目

线性分子式:

(C₆H₅)₂SiH₂

化学文摘社编号:

775-12-2

分子量:

184.31

UNSPSC Code:

12352103

NACRES:

NA.22

PubChem Substance ID:

24848906

EC Number:

212-271-4

Beilstein/REAXYS Number:

2935887

MDL number:

MFCD00003002

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属性

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.579 (lit.)

bp

95-97 °C/13 mmHg (lit.)

density

0.993 g/mL at 25 °C (lit.)

SMILES string

[SiH2](c1ccccc1)c2ccccc2

InChI

1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

InChI key

VDCSGNNYCFPWFK-UHFFFAOYSA-N

说明

General description

二苯基硅烷是子有机硅化合物，可用作酰胺键偶联试剂& 烯烃氢化硅烷化（hydrosilylation）前体。

Application

双二苯基硅烷的制备及其阳离子型UV固化材料性能研究：研究探讨了使用二苯基硅烷的新材料的合成和光敏性，强调了其在UV固化应用中的潜力（Y Liu et al., 2021, MDPI）。

基于双(3,5-二(9H-咔唑-9-基))二苯基硅烷的喷墨打印蓝色磷光发光层：研究使用二苯基硅烷衍生物开发用于喷墨打印的蓝色磷光材料，也可用于电子显示器（R Bail et al., 2018, RSC Advances。

存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

208.4 °F - closed cup

flash_point_c

98 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

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Diphenylsilane as a coupling reagent for amide bond formation

Sayes, Morgane, et al.

Green Chemistry, 19, 5060-5064 (2017)

Reactions of Zirconium (IV) n-Propoxide with SiH-Functional Polysiloxanes as a Route to Siloxane-Zirconium Hybrid Materials with Enhanced Refractive Index.

Slawomir Rubinsztajn et al.

Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)

The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained

High Performance Redox Initiating Systems Based on the Interaction of Silane with Metal Complexes: A Unique Platform for the Preparation of Composites.

Ahmad Arar et al.

Molecules (Basel, Switzerland), 25(7) (2020-04-05)

Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace

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全球贸易项目编号

货号	GTIN
148482-5G	04061838737960
148482-25G	04061838737953