148482
二苯基硅烷
97%
别名:
Diphenyl silane, Diphenylsilicon
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.579 (lit.)
沸点
95-97 °C/13 mmHg (lit.)
密度
0.993 g/mL at 25 °C (lit.)
SMILES字符串
[SiH2](c1ccccc1)c2ccccc2
InChI
1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2
InChI key
VDCSGNNYCFPWFK-UHFFFAOYSA-N
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一般描述
二苯基硅烷是子有机硅化合物，可用作酰胺键偶联试剂& 烯烃氢化硅烷化（hydrosilylation）前体。
应用
- 双二苯基硅烷的制备及其阳离子型UV固化材料性能研究：研究探讨了使用二苯基硅烷的新材料的合成和光敏性，强调了其在UV固化应用中的潜力（Y Liu et al., 2021, MDPI）。
- 基于双(3,5-二(9H-咔唑-9-基))二苯基硅烷的喷墨打印蓝色磷光发光层：研究使用二苯基硅烷衍生物开发用于喷墨打印的蓝色磷光材料，也可用于电子显示器（R Bail et al., 2018, RSC Advances。
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
208.4 °F - closed cup
闪点(°C)
98 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Diphenylsilane as a coupling reagent for amide bond formation
Sayes, Morgane, et al.
Green Chemistry, 19, 5060-5064 (2017)
Ahmad Arar et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-05)
Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace
Saravanan Karuppiah et al.
ACS nano, 14(9), 12006-12015 (2020-09-10)
Silicon (Si) is the most promising anode candidate for the next generation of lithium-ion batteries but difficult to cycle due to its poor electronic conductivity and large volume change during cycling. Nanostructured Si-based materials allow high loading and cycling stability
Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained
Christopher L Rock et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 461-467 (2018-11-30)
The phosphine-substituted α-diimine Ni precursor, (Ph2PPrDI)Ni, has been found to catalyze alkene hydrosilylation in the presence of Ph2SiH2 with turnover frequencies of up to 124 h-1 at 25 °C (990 h-1 at 60 °C). Moreover, the selective hydrosilylation of allylic
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