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Merck
CN

148938

Sigma-Aldrich

2-碘丙烷

contains copper as stabilizer, 99%

别名:

异丙基碘

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About This Item

线性分子式:
(CH3)2CHI
CAS号:
分子量:
169.99
Beilstein:
1098244
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

99%

表单

liquid

包含

copper as stabilizer

折射率

n20/D 1.498 (lit.)

沸点

88-90 °C (lit.)

mp

−90 °C (lit.)

密度

1.703 g/mL at 25 °C (lit.)

官能团

alkyl halide
iodo

SMILES字符串

CC(C)I

InChI

1S/C3H7I/c1-3(2)4/h3H,1-2H3

InChI key

FMKOJHQHASLBPH-UHFFFAOYSA-N

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一般描述

2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂,用于制备 α-异丙氧基亚甲基保护基团。此外,它还作为硫代碳酸盐转化为烯烃的中间体。

应用

2-碘丙烷(异丙基碘)被用于制备丁酸和异丁酸

2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物(吲哚、吡啶、嘌呤、四唑、吡唑和胺)转化为对应产物。

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

107.6 °F - closed cup

闪点(°C)

42 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
Shanshan Zhang et al.
Analytica chimica acta, 978, 24-34 (2017-06-10)
Stable isotope chemical labeling liquid chromatography-mass spectrometry (LC-MS) is a powerful strategy for comprehensive metabolomics profiling, which can improve metabolites coverage and quantitative information for exploration of metabolic regulation in complex biological systems. In the current work, a novel stable
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate

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