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Merck
CN

148938

2-碘丙烷

contains copper as stabilizer, 99%

别名:

异丙基碘

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关于此项目

线性分子式:
(CH3)2CHI
化学文摘社编号:
分子量:
169.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-859-3
Beilstein/REAXYS Number:
1098244
MDL number:
Assay:
99%
Form:
liquid
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Quality Level

assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.498 (lit.)

bp

88-90 °C (lit.)

mp

−90 °C (lit.)

density

1.703 g/mL at 25 °C (lit.)

functional group

alkyl halide, iodo

SMILES string

CC(C)I

InChI

1S/C3H7I/c1-3(2)4/h3H,1-2H3

InChI key

FMKOJHQHASLBPH-UHFFFAOYSA-N

General description

2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂,用于制备 α-异丙氧基亚甲基保护基团。此外,它还作为硫代碳酸盐转化为烯烃的中间体。

Application

2-碘丙烷(异丙基碘)被用于制备丁酸和异丁酸

2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物(吲哚、吡啶、嘌呤、四唑、吡唑和胺)转化为对应产物。


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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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Lot/Batch Number

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Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)



全球贸易项目编号

货号GTIN
148938-500G04061838738103
148938-5G04061838738110
148938-100G04061838738097