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149845

乙醇铊(I)

Name: 乙醇铊(I)
Brand: ALDRICH

别名:

乙醇铊盐, 乙醇铊（I）盐, 铊一氧化硒, 乙氧基亚铊

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关于此项目

线性分子式:

TlOC₂H₅

化学文摘社编号:

20398-06-5

分子量:

249.44

NACRES:

NA.22

PubChem Substance ID:

24848978

UNSPSC Code:

12352300

EC Number:

243-786-2

MDL number:

MFCD00009072

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属性

form

liquid

Quality Level

100

reaction suitability

core: thallium, reagent type: catalyst

refractive index

n20/D 1.676 (lit.)

density

3.522 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCO[Tl]

InChI

1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1

InChI key

DZFYOYRNBGNPJW-UHFFFAOYSA-N

说明

Application

用HCl还原各种官能团；羰基化合物的立体选择性烯丙基化；原位生成锡烯醇化物用于定向羟醛反应。

pictograms

GHS06,GHS08,GHS09

signalword

Danger

hcodes

H300 + H330,H373,H411

pcodes

P260 - P264 - P271 - P273 - P304 + P340 + P310 - P314

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

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Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation.

Yann Sarazin et al.

Journal of the American Chemical Society, 129(4), 881-894 (2007-01-25)

The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound

Andrews, P. C.; Peatt, A. C.; Raston, C. L.

Tetrahedron Letters, 43, 7541-7541 (2002)

Effectiveness of sodium sugar sulfates on acute toxicity of paraquat in mice.

T Tsuchiya et al.

Journal of pharmacobio-dynamics, 12(8), 456-460 (1989-08-01)

The reduction of acute toxicity of paraquat dichloride (PQ) in mice was studied by several sodium sugar sulfates such as dextran sulfate (DS), cellulose sulfate (CS), chondroitin sulfate (CDS), sucrose sulfate (SS) and glucose sulfate (GS). When sugar sulfates (DS

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全球贸易项目编号

货号	GTIN
10452-10G	04061838671899
149845-25G	04061838134783
149845-5G	04061838738486