149845
乙醇铊(I)
别名:
乙醇铊盐, 乙醇铊（I）盐, 铊一氧化硒, 乙氧基亚铊
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线性分子式:
TlOC2H5
化学文摘社编号:
分子量:
249.44
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
243-786-2
MDL number:
form
liquid
InChI key
DZFYOYRNBGNPJW-UHFFFAOYSA-N
InChI
1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1
SMILES string
CCO[Tl]
reaction suitability
core: thallium
reagent type: catalyst
refractive index
n20/D 1.676 (lit.)
density
3.522 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
用HCl还原各种官能团；羰基化合物的立体选择性烯丙基化；原位生成锡烯醇化物用于定向羟醛反应。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Andrews, P. C.; Peatt, A. C.; Raston, C. L.
Tetrahedron Letters, 43, 7541-7541 (2002)
Yann Sarazin et al.
Journal of the American Chemical Society, 129(4), 881-894 (2007-01-25)
The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound
T Tsuchiya et al.
Journal of pharmacobio-dynamics, 12(8), 456-460 (1989-08-01)
The reduction of acute toxicity of paraquat dichloride (PQ) in mice was studied by several sodium sugar sulfates such as dextran sulfate (DS), cellulose sulfate (CS), chondroitin sulfate (CDS), sucrose sulfate (SS) and glucose sulfate (GS). When sugar sulfates (DS
Chan, T. H.; Li, C. J.; Wei, Z. Y.,
Journal of the Chemical Society. Chemical Communications, 505-505 (1990)
Michel J Kohl et al.
Steroids, 67(1), 71-75 (2001-12-01)
Conjugation of haptens through ether linkages avoids leakage problems in immunoassays, but this procedure is not easily applied to most steroids that bear low reacting hydroxyls. A new technique allowing the ether coupling of biologically active steroids with conjugating arms
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