150533
三氟乙酸铊(III)
technical grade
别名:
TTFA, 三氟乙酸铊(III), 三氟乙酸 铊(III) 盐, 三氟醋酸铊
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关于此项目
线性分子式:
(CF3COO)3Tl
CAS Number:
分子量:
543.43
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
等级
technical grade
质量水平
反应适用性
core: thallium
reagent type: catalyst
mp
213 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
FC(F)(F)C(=O)O[Tl](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F
InChI
1S/3C2HF3O2.Tl/c3*3-2(4,5)1(6)7;/h3*(H,6,7);/q;;;+3/p-3
InChI key
PSHNNUKOUQCMSG-UHFFFAOYSA-K
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应用
氧化剂,用于合成 S-取代的半胱氨酸肽和含有二硫键的蛋白质。
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Luis Julià et al.
Magnetic resonance in chemistry : MRC, 49(4), 164-167 (2011-03-26)
Electron paramagnetic resonance (EPR) analysis of neutral and acidic solutions of 2,5-dimethyl-1-phenylpyrrol (1) and meta-, para-, and ortho-bis(2,5-dimethylpyrrol-1-yl)benzenes (4-6) in the presence of Tl(III) trifluoroacetate as oxidant reveals the poor stability of their generated monomeric radical cations which dimerize through
Rui Tang et al.
Journal of natural medicines, 74(2), 495-500 (2020-02-01)
Cancer cells adapted to the microenvironment in tumor such as hypoxic and nutrient-starved conditions are now paid much attention as the therapeutic target of cancer. In the course of search for selective cytotoxic substances against cancer cells adapted to nutrient
Journal of the Chemical Society. Chemical Communications, 163-163 (1987)
Taylor, E. C.; Katz, A. H. et al.
Tetrahedron Letters, 26, 5963-5963 (1985)
Deacon, G. B.; Smith, R. N. M.
Journal of Fluorine Chemistry, 15, 85-85 (1980)
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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