150533
三氟乙酸铊(III)
technical grade
别名:
TTFA, 三氟乙酸铊(III), 三氟乙酸 铊(III) 盐, 三氟醋酸铊
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关于此项目
线性分子式:
(CF3COO)3Tl
CAS Number:
分子量:
543.43
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
等级
technical grade
质量水平
反应适用性
core: thallium
reagent type: catalyst
mp
213 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
FC(F)(F)C(=O)O[Tl](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F
InChI
1S/3C2HF3O2.Tl/c3*3-2(4,5)1(6)7;/h3*(H,6,7);/q;;;+3/p-3
InChI key
PSHNNUKOUQCMSG-UHFFFAOYSA-K
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应用
氧化剂，用于合成 S-取代的半胱氨酸肽和含有二硫键的蛋白质。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Luis Julià et al.
Magnetic resonance in chemistry : MRC, 49(4), 164-167 (2011-03-26)
Electron paramagnetic resonance (EPR) analysis of neutral and acidic solutions of 2,5-dimethyl-1-phenylpyrrol (1) and meta-, para-, and ortho-bis(2,5-dimethylpyrrol-1-yl)benzenes (4-6) in the presence of Tl(III) trifluoroacetate as oxidant reveals the poor stability of their generated monomeric radical cations which dimerize through
Journal of the Chemical Society. Chemical Communications, 163-163 (1987)
Deacon, G. B.; Smith, R. N. M.
Journal of Fluorine Chemistry, 15, 85-85 (1980)
Cuihua Hu et al.
Molecular pharmaceutics, 16(2), 561-572 (2018-12-29)
The chimeric peptide HPRP-A1-iRGD, composed of a chemically conjugated tumor-homing/penetration domain (iRGD) and a cationic anticancer peptide domain (HPRP-A1), was used to study the effect of targeted modification to enhance the peptide's specificity, penetration, and tumor accumulation ability. The iRGD
Taylor, E. C.; Katz, A. H. et al.
Tetrahedron Letters, 26, 5963-5963 (1985)
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