151386
富马酰氯
95%
别名:
(2E)-2-丁烯二酰二氯, 二氯富马酸, 富马酸二氯化物, 富马酸酰氯
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线性分子式:
ClCOCH=CHCOCl
化学文摘社编号:
分子量:
152.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-005-4
Beilstein/REAXYS Number:
1721342
MDL number:
Assay:
95%
Form:
liquid
form
liquid
InChI key
ZLYYJUJDFKGVKB-OWOJBTEDSA-N
InChI
1S/C4H2Cl2O2/c5-3(7)1-2-4(6)8/h1-2H/b2-1+
SMILES string
ClC(=O)\C=C\C(Cl)=O
assay
95%
refractive index
n20/D 1.499 (lit.)
bp
161-164 °C (lit.)
density
1.415 g/mL at 25 °C (lit.)
functional group
acyl chloride
storage temp.
2-8°C
Quality Level
General description
研究了富马酰氯的光解动力学 。
Application
富马酰氯用于制备高分子量富马酸聚丙烯酯 。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Monali Kawade et al.
The journal of physical chemistry. A, 115(9), 1538-1546 (2011-02-17)
The photodissociation dynamics of fumaryl chloride (ClCO-CH═CH-COCl) has been studied in a supersonic molecular beam around 235 nm using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique by detecting the nascent state of the primary chlorine atom. A single laser
Seyed Amin Mirmohammadi et al.
Materials science & engineering. C, Materials for biological applications, 68, 530-539 (2016-08-16)
Hydroxyl functionalized nano-sized POSS or ethyleneglycol as diol monomers was incorporated to hydroxyl-terminated polybutadiene (HTPBD) chain in the presence of fumaryl chloride as extender. Blue light photocrosslinking system based on camphorquinone (photoinitiator) and dimethylaminoethyl methacrylate (accelerator) was applied to cure
Sepideh Koosehgol et al.
Materials science & engineering. C, Materials for biological applications, 79, 66-75 (2017-06-21)
In the present study, polyethylene glycol fumarate (PEGF) was synthesized as a component of blend solutions via polycondensation polymerization and characterized by different tests in order to determine its functional groups and its physical properties included melting and crystallization temperature
S J Peter et al.
Journal of biomaterials science. Polymer edition, 10(3), 363-373 (1999-04-03)
To synthesize high molecular weight poly(propylene fumarate) (PPF), fumaryl chloride and propylene glycol were reacted in the presence of potassium carbonate, which serves as a proton scavenger. Transesterification of the resulting low molecular weight oligomer led to a polymer with
Elham Shamirzaei Jeshvaghani et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 106(6), 2371-2383 (2017-11-24)
With regard to flexibility and strength properties requirements of soft biological tissue, elastomeric materials could be more beneficial in soft tissue engineering applications. The present work investigates the use of an elastic polymer, (polycaprolactone fumarate [PCLF]), for fabricating an electrospun
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