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安全信息

151386

Sigma-Aldrich

富马酰氯

95%

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别名:
(2E)-2-Butenedioyl dichloride, Fumaric acid chloride, Fumaric acid dichloride, Fumaric dichloride, Fumaroyl dichloride, Fumaryl dichloride
线性分子式:
ClCOCH=CHCOCl
CAS号:
627-63-4
分子量:
152.96
Beilstein:
1721342
EC 号:
211-005-4
MDL编号:
MFCD00000733
PubChem化学物质编号:
24849125
NACRES:
NA.22

检测方案

95%

形式

liquid

折射率

n20/D 1.499 (lit.)

bp

161-164 °C (lit.)

密度

1.415 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES string

ClC(=O)\C=C\C(Cl)=O

InChI

1S/C4H2Cl2O2/c5-3(7)1-2-4(6)8/h1-2H/b2-1+

InChI key

ZLYYJUJDFKGVKB-OWOJBTEDSA-N

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相关类别

一般描述

研究了富马酰氯的光解动力学 。

应用

富马酰氯用于制备高分子量富马酸聚丙烯酯 。

象形图

CorrosionExclamation mark
GHS05,GHS07

警示用语：

Danger

危险声明

H302 + H312 - H314

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

170.6 °F - closed cup

闪点(°C)

77 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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N Piétri et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(1), 157-165 (2000-03-23)
Fourier transform infrared spectra of fumaryl chloride 1 isolated in an argon matrix at 10 K have been analyzed. The comparison between the ab initio HF/6-31G calculated infrared spectra with the experimental ones reveals the existence of three planar conformers
Monali Kawade et al.
The journal of physical chemistry. A, 115(9), 1538-1546 (2011-02-17)
The photodissociation dynamics of fumaryl chloride (ClCO-CH═CH-COCl) has been studied in a supersonic molecular beam around 235 nm using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique by detecting the nascent state of the primary chlorine atom. A single laser
Seyed Amin Mirmohammadi et al.
Materials science & engineering. C, Materials for biological applications, 68, 530-539 (2016-08-16)
Hydroxyl functionalized nano-sized POSS or ethyleneglycol as diol monomers was incorporated to hydroxyl-terminated polybutadiene (HTPBD) chain in the presence of fumaryl chloride as extender. Blue light photocrosslinking system based on camphorquinone (photoinitiator) and dimethylaminoethyl methacrylate (accelerator) was applied to cure
Elham Shamirzaei Jeshvaghani et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 106(6), 2371-2383 (2017-11-24)
With regard to flexibility and strength properties requirements of soft biological tissue, elastomeric materials could be more beneficial in soft tissue engineering applications. The present work investigates the use of an elastic polymer, (polycaprolactone fumarate [PCLF]), for fabricating an electrospun
S J Peter et al.
Journal of biomaterials science. Polymer edition, 10(3), 363-373 (1999-04-03)
To synthesize high molecular weight poly(propylene fumarate) (PPF), fumaryl chloride and propylene glycol were reacted in the presence of potassium carbonate, which serves as a proton scavenger. Transesterification of the resulting low molecular weight oligomer led to a polymer with
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