151599
三氯乙酰氯
99%
别名:
2,2,2-三氯乙酰氯, 三氯乙酰氯
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线性分子式:
Cl3CCOCl
化学文摘社编号:
分子量:
181.83
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-926-7
Beilstein/REAXYS Number:
774120
MDL number:
Assay:
99%
Form:
liquid
refractive index
n20/D 1.470 (lit.)
bp
114-116 °C (lit.)
mp
−57 °C (lit.)
density
1.629 g/mL at 25 °C (lit.)
functional group
acyl chloride, chloro
InChI key
PVFOMCVHYWHZJE-UHFFFAOYSA-N
InChI
1S/C2Cl4O/c3-1(7)2(4,5)6
SMILES string
ClC(=O)C(Cl)(Cl)Cl
vapor pressure
16 mmHg ( 20 °C)
assay
99%
form
liquid
Quality Level
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General description
氯化三氯乙酰，又称2,2,2-三氯乙酰氯，是一种不对称酮。在实验室中常用作氯原子源。也作为酰化剂制备双(三氯乙酰)环烯胺类化合物。
Application
三氯乙酰氯可用于制备二氢-1H-苯并吲哚，还用于合成3-烷基苯并恶唑酮。
signalword
Danger
flash_point_f
213.8 °F - open cup
flash_point_c
101 °C - open cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
法规信息
新产品
此项目有
Jianqiang Zhu et al.
The journal of physical chemistry. A, 121(36), 6800-6809 (2017-08-25)
Rate constants at room temperature (293 ± 2 K) and atmospheric pressure for the reaction of methyl n-propyl ether (MnPE), CH
B Roig et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(13), 2925-2930 (2002-12-13)
Within the framework of the monitoring of the trichloroacetylchloride (TCAC) photosynthesis, ultra-violet (UV) spectrophotometry is proposed as a simple and rapid tool allowing, in real time, the control of the process efficiency. A good correlation has been obtained between the
E Eliasson et al.
Chemico-biological interactions, 116(1-2), 123-141 (1999-01-07)
Halothane hepatitis occurs because susceptible patients mount immune responses to trifluoroacetylated protein antigens, formed following cytochrome P450-mediated bioactivation of halothane to trifluoroacetyl chloride. In the present study, an in vitro approach has been used to investigate the cytochrome P450 isozyme(s)
A M Saillenfait et al.
Archives of toxicology, 70(2), 71-82 (1995-01-01)
The embryotoxicity of trichloroethylene (TRI), tetrachloroethylene (PER), and of four of their oxidative metabolites i.e. trichloroacetic acid, dichloroacetic acid, chloral hydrate, and trichloroacetyl chloride, was studied in vitro, using the rat whole embryo culture system. Embryos from Sprague-Dawley rats were
Ram N Ram et al.
The Journal of organic chemistry, 78(23), 11935-11947 (2013-10-31)
Benzoxazolone pharmacophore is present in clinical pharmaceuticals, drug candidates, and many compounds having a wide spectrum of biological activities. The methods available for the synthesis of benzoxazolones have limited diversity due to problems in accessibility and air-sensitivity of diversely substituted
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