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Merck
CN

15512

Boc-Trp-OH

≥99.0% (TLC)

别名:

Nα-(叔丁氧羰基)-L-色氨酸, Nα-Boc-L-色氨酸

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关于此项目

经验公式(希尔记法):
C16H20N2O4
化学文摘社编号:
分子量:
304.34
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352209
EC Number:
236-072-7
MDL number:
Beilstein/REAXYS Number:
39677
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产品名称

Boc-Trp-OH, ≥99.0% (TLC)

InChI key

NFVNYBJCJGKVQK-ZDUSSCGKSA-N

InChI

1S/C16H20N2O4/c1-16(2,3)22-15(21)18-13(14(19)20)8-10-9-17-12-7-5-4-6-11(10)12/h4-7,9,13,17H,8H2,1-3H3,(H,18,21)(H,19,20)/t13-/m0/s1

SMILES string

CC(C)(C)OC(=O)N[C@@H](Cc1c[nH]c2ccccc12)C(O)=O

assay

≥99.0% (TLC)

optical activity

[α]20/D −20±1°, c = 1% in DMF

reaction suitability

reaction type: Boc solid-phase peptide synthesis

mp

136 °C (dec.) (lit.)

application(s)

peptide synthesis

Quality Level

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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bailey T , et al. et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 21 (2014)
Peroxidase catalyzed nitration of tryptophan derivatives
Sala A, et al.
European Journal of Biochemistry, 271(13), 2841-2852 (2004)
R Vespalec et al.
Electrophoresis, 19(2), 276-281 (1998-04-21)
An equation for the calculation of electrophoretic mobility of kinetically labile complexes originating in solutions during the chiral discrimination process is derived. The mobility of the complex is calculated from that of a fully ionized racemic compound, measured in absence
Y Kato et al.
Biochemical and biophysical research communications, 234(1), 82-84 (1997-05-08)
The aim of this study was to clarify the mechanism of loss of Trp residues in proteins exposed to peroxynitrite. The Trp residues in bovine serum albumin and collagen IV were decreased by peroxynitrite treatment. To identify the degradation products
R Magous et al.
Biochimica et biophysica acta, 845(2), 158-162 (1985-05-30)
Benzotript (N-p-chlorobenzoyl-L-tryptophan) has been shown to be a receptor-antagonist in vivo and in vitro for peptides from the gastrin family. In the present study, we examine tryptophan, and some of its N- and C-acylated derivatives, as well as some phenylalanine

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