157120
4-叔丁基苯甲酰氯
98%
别名:
4-(1,1-Dimethylethyl)benzoyl chloride, 4-tert-Butylbenzoic acid chloride, p-tert-Butylbenzoyl chloride
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关于此项目
线性分子式:
(CH3)3CC6H4COCl
化学文摘社编号:
分子量:
196.67
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-973-1
Beilstein/REAXYS Number:
775793
MDL number:
产品名称
4-叔丁基苯甲酰氯, 98%
InChI key
WNLMYNASWOULQY-UHFFFAOYSA-N
InChI
1S/C11H13ClO/c1-11(2,3)9-6-4-8(5-7-9)10(12)13/h4-7H,1-3H3
SMILES string
CC(C)(C)c1ccc(cc1)C(Cl)=O
assay
98%
form
liquid
refractive index
n20/D 1.536 (lit.)
bp
135 °C/20 mmHg (lit.)
density
1.007 g/mL at 25 °C (lit.)
functional group
acyl chloride
Quality Level
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Application
4-tert-Butylbenzoyl chloride was used in the synthesis of 9,9′-spirobifluorene-bridged bipolar systems containing 1,3,4-oxadiazole-conjugated oligoaryl and triaryllamine moieties. It was also used in the preparation of 2-(4-tert-butylphenyl)-5-(4-methoxyphenyl)-1,3,4-oxadiazole.
General description
AlCl3 promoted Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene was investigated.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
188.6 °F - closed cup
flash_point_c
87 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Yuh-Yih Chien et al.
Chemical communications (Cambridge, England), (23)(23), 2874-2875 (2002-12-14)
Some 9,9'-spirobifluorene-bridged bipolar systems 1-3 containing 1,3,4-oxadiazole-conjugated oligoaryl and triarylamine moieties have been synthesized, in which 1 exhibits remarkable solvent-polarity dependent fluorescence properties due to a highly efficient photoinduced electron transfer reaction.
Statistical copolymers with side-chain hole and electron transport groups for single-layer electroluminescent device applications.
Jiang X, et al.
Chemistry of Materials, 12(9), 2542-2549 (2000)
Zhiliang Huang et al.
Organic & biomolecular chemistry, 11(11), 1810-1814 (2013-02-08)
AlCl(3) promoted Friedel-Crafts acylation between 4-tert-butylbenzoyl chloride and mesitylene was investigated. The donor-acceptor complex was observed as the major species. Kinetic investigation demonstrated that the reaction was first-order on the donor-acceptor complex and zero-order on ArH, suggesting that the donor-acceptor
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