157635
7,7,8,8-四氰基对苯二醌二甲烷
98%
别名:
2,2′-(2,5-环己二烯-1,4-二基)丙二腈, TCNQ
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关于此项目
经验公式（希尔记法）:
C12H4N4
化学文摘社编号:
分子量:
204.19
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
216-174-8
Beilstein/REAXYS Number:
1427366
MDL number:
Quality Level
assay
98%
form
solid
mp
287-289 °C (dec.) (lit.)
orbital energy
LUMO 4.6 eV
semiconductor properties
N-type (mobility=10−5 cm2/V·s)
SMILES string
N#C\C(C#N)=C1/C=C\C(C=C1)=C(/C#N)C#N
InChI
1S/C12H4N4/c13-5-11(6-14)9-1-2-10(4-3-9)12(7-15)8-16/h1-4H
InChI key
PCCVSPMFGIFTHU-UHFFFAOYSA-N
Gene Information
human ... CAPN1(823)
rat ... Capn1(29153), Nos1(24598)
General description
7,7,8,8-四氰基对苯醌二甲烷(TNCQ)是强电子受体，它有四个氰基和π-共轭键，可形成电荷转移链和离子自由基盐，主要用作p掺杂剂，用于各种半导体制造应用。
Application
四硫代并四苯(TTT)和TNCQ可热共沉积以形成n型薄膜， 功率因数为0.33 μWm-1K-2，导电率为57 Sm-1，用于制造薄膜有机热电发电机。该物质可用于功能化化学气相沉积(CVD)石墨烯，形成p掺杂纳米复合材料，有望应用于有机太阳能电池(OSC)的导电阳极。电化学传感器可使用TNCQ和石墨烯氧化物开发，以形成玻璃电极，用于检测谷胱甘肽(GSH)的降低。
用于形成电荷转移超导体的电子受体分子。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Rajsapan Jain et al.
Nature, 445(7125), 291-294 (2007-01-19)
For over two decades there have been intense efforts aimed at the development of alternatives to conventional magnets, particularly materials comprised in part or wholly of molecular components. Such alternatives offer the prospect of realizing magnets fabricated through controlled, low-temperature
Characterisation of two distinctly different processes associated with the electrocrystallization of microcrystals of phase I CuTCNQ (TCNQ= 7, 7, 8, 8-tetracyanoquinodimethane)
Harris, Alexander R., et al.
Journal of Materials Chemistry, 16(45), 4397-4406 (2006)
Liang Pan et al.
Nature communications, 11(1), 1332-1332 (2020-03-14)
Compared to transmission systems based on shafts and gears, tendon-driven systems offer a simpler and more dexterous way to transmit actuation force in robotic hands. However, current tendon fibers have low toughness and suffer from large friction, limiting the further
(Pro2 H+)2 (TCNQ.-)2⋅TCNQ: an amino acid derived semiconductor.
Xiaohu Qu et al.
Angewandte Chemie (International ed. in English), 50(7), 1589-1592 (2011-02-11)
The crystal and molecular structure of 7, 7, 8, 8-tetracyanoquinodimethane
Long, R. E., Sparks, R. A., & Trueblood, K. N.
Acta Crystallographica, 18(5), 932-939 (1965)
商品
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 157635-10G | 04061838743442 |
| 157635-5G | 04061838743459 |
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