157872
1,3-二噻烷
97%
别名:
间二噻烷（7CI）, 间二噻烷（8CI）
质量水平
方案
97%
表单
solid
mp
52-54 °C (lit.)
官能团
thioether
SMILES字符串
C1CSCSC1
InChI
1S/C4H8S2/c1-2-5-4-6-3-1/h1-4H2
InChI key
WQADWIOXOXRPLN-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
1,3-二噻烷，一种受保护的甲醛阴离子当量，用作有用的标记合成子。
应用
以 1，3-二噻烷为脱氧剂，将亚砜脱氧成相应的硫化物。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
194.0 °F - closed cup
闪点(°C)
90 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Rodolfo A Martinez et al.
Journal of labelled compounds & radiopharmaceuticals, 57(5), 338-341 (2014-05-28)
The 1,3-dithiane is a protected formaldehyde anion equivalent that could serve as a useful labeled synthon. We report a facile synthesis of 1,3-[2-(13)C]- and 1,3-[2-(13)C, 2-(2)H2]dithiane in two steps from [(13)C]- or [(13) C, (2)H3 ]methyl phenyl sulfoxide. We have
Valerie J Peterson et al.
The Biochemical journal, 362(Pt 1), 173-181 (2002-02-07)
Apo and holo forms of retinoic acid receptors, and other nuclear receptors, display differential sensitivity to proteolytic digestion that likely reflects the distinct conformational states of the free and liganded forms of the receptor. We have developed a method for
Padmanabha V Kattamuri et al.
The Journal of organic chemistry, 76(8), 2792-2797 (2011-03-17)
A series of α-amino-1,3-dithianes have been synthesized via the asymmetric Umpolung reaction of 2-lithio-1,3-dithianes with chiral N-phosphonyl imines in good chemical yields (up to 82%) and good to excellent diastereoselectivities (>99:1). The manner by which chiral N-phosphonyl imines are slowly
Al-Monsur Jiaul Haque et al.
Chemical communications (Cambridge, England), (32)(32), 4865-4867 (2009-08-05)
We report the use of 1,3-dithiane combined with aryldiazonium cation for the immobilization of biomolecules based on electrochemical addressing.
A I Noskov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 77(1), 6-10 (2010-07-17)
The IR spectra of 1,3-dithiane-1-oxide (I) and 1,3-dithia-1-oxocyclohept-5-ene (II) were recorded in solution, solid and liquid phase over 4000-400 cm(-1) spectral range. It was found that both (I) and (II) in liquid phase and solutions exist in two conformations: (I)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持