157910
溴乙酸甲酯
97%
别名:
2-溴乙酸甲酯, 2-溴代乙酸甲酯, 溴乙酸甲酯, 甲基α-溴乙酸, 甲氧基甲基溴
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线性分子式:
BrCH2COOCH3
化学文摘社编号:
分子量:
152.97
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-499-2
Beilstein/REAXYS Number:
506256
MDL number:
产品名称
溴乙酸甲酯, 97%
InChI key
YDCHPLOFQATIDS-UHFFFAOYSA-N
InChI
1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3
SMILES string
COC(=O)CBr
assay
97%
form
liquid
refractive index
n20/D 1.458 (lit.)
bp
51-52 °C/15 mmHg (lit.)
density
1.616 g/mL at 25 °C (lit.)
functional group
bromo
ester
Quality Level
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Application
溴乙酸甲酯用于合成新型香豆素。它还用于合成顺式-环丙烷。
General description
溴乙酸甲酯是一种α-溴酯。溴乙酸甲酯与（甲氧基卡宾）五羰基铬（0）的共轭碱反应生成烷基化卡宾络合物。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
147.2 °F - closed cup
flash_point_c
64 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Yasameen K Al-Majedy et al.
Molecules (Basel, Switzerland), 19(8), 11791-11799 (2014-08-12)
Some novel coumarins were synthesized starting from 4-hydroxycoumarin and methyl bromoacetate. The structures of the newly obtained compounds were confirmed by elemental analysis, mass, IR and NMR spectra.
Reactions of conjugate bases of metal carbene complexes with expoxides and with a-bromo esters.
Casey CP and Anderson RL.
Journal of Organometallic Chemistry, 73(2), C28-C30 (1974)
One-pot method for stereoselective cyclopropanation of electron-deficient olefins with methyl bromoacetate and phenacyl bromide in the presence of triphenylarsine.
Ren Z, et al.
Synthesis, 2005(16), 2718-2722 (2005)
Hailemichael Ayalew et al.
Polymers, 11(4) (2019-04-13)
Deprotonation-induced conductivity shift of poly(3,4-ethylenedixoythiophene)s (PEDOTs) in aqueous solutions is a promising platform for chemical or biological sensor due to its large signal output and minimum effect from material morphology. Carboxylic acid group functionalized poly(Cn-EDOT-COOH)s are synthesized and electrodeposited on
Josef Dib et al.
Journal of mass spectrometry : JMS, 50(2), 407-417 (2015-03-25)
AdipoR agonists are small, orally active molecules capable of mimicking the protein adiponectin, which represents an adipokine with antidiabetic and antiatherogenic effects. Two adiponectin receptors were reported in the literature referred to as adipoR1 and adipoR2. Activation of these receptors
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