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Merck
CN

158402

二环己烷并-18-冠醚-6

98%

别名:

2,3,11,12-双环己基-1,4,7,10,13,16-六氧环十八烷, 2,5,8,15,18,21-六氧杂三环[20.4.0.09.14]二十六烷, 二环己基并-18-冠醚-6, 全氢-二苯并-18-冠-6

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关于此项目

经验公式(希尔记法):
C20H36O6
化学文摘社编号:
分子量:
372.50
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-216-4
Beilstein/REAXYS Number:
1130529
MDL number:
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产品名称

二环己烷并-18-冠醚-6, 98%

InChI key

BBGKDYHZQOSNMU-UHFFFAOYSA-N

InChI

1S/C20H36O6/c1-2-6-18-17(5-1)23-13-9-21-11-15-25-19-7-3-4-8-20(19)26-16-12-22-10-14-24-18/h17-20H,1-16H2

SMILES string

C1CCC2OCCOCCOC3CCCCC3OCCOCCOC2C1

assay

98%

form

solid

functional group

ether

Quality Level

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Application

阴离子活化剂,并作为络合剂溶解非极性溶剂中的碱金属离子。

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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P Arhem et al.
Acta physiologica Scandinavica, 114(4), 593-600 (1982-04-01)
A potassium carrying ionophore dicyclohexano-18-crown-6 was found to affect the specific ionic currents in the node of Ranvier. Its presence caused an inactivation of the potassium permeability mechanism and a decrease of the sodium permeability. The rate of inactivation of
Aldrichimica Acta, 9, 3-3 (1976)
Giorgio Della Sala et al.
Organic & biomolecular chemistry, 11(5), 726-731 (2012-11-03)
The synthesis, complexation properties and catalytic activities under phase-transfer (PT) conditions of differently substituted cyclohexapeptoids are reported. Association constants, for small cationic alkali, and catalytic performances, in a model nucleophilic substitution, are comparable to those of representative crown ethers. Noteworthy
Aldrichimica Acta, 4, 1-1 (1971)
Svetlana V Smirnova et al.
Analytical and bioanalytical chemistry, 378(5), 1369-1375 (2004-01-30)
Amino acids Trp, Gly, Ala, Leu are extracted efficiently from aqueous solution at pH 1.5-4.0 (Lys and Arg at pH 1.5-5.5) into the room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF(6)) with dicyclohexano-18-crown-6 (CE). The most hydrophilic amino acids such as

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