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159069

4-氯苯甲醚

Name: 4-氯苯甲醚
Brand: ALDRICH

99%

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关于此项目

线性分子式:

ClC₆H₄OCH₃

化学文摘社编号:

623-12-1

分子量:

142.58

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24849788

EC Number:

210-772-2

Beilstein/REAXYS Number:

1858901

MDL number:

MFCD00000616

Assay:

99%

Form:

liquid

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属性

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.535 (lit.)

bp

198-202 °C (lit.)

mp

−18 °C (lit.)

density

1.164 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

COc1ccc(Cl)cc1

InChI

1S/C7H7ClO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

InChI key

YRGAYAGBVIXNAQ-UHFFFAOYSA-N

说明

General description

4-氯茴香醚是一种富含电子的氯芳烃。它在原位生成的钯胶体催化下进行了乌尔曼型均偶联。正己烷、四氯化碳或二氯甲烷中4-氯茴香醚与铜（II）-蒙脱石的反应已被研究。4-氯茴香醚的亲核取代反应、光化学反应和光水解反应已通过时间分辨光谱法进行了研究。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Single electron transfer mechanism of oxidative dechlorination of 4-chloroanisole on copper (II)-smectite.

Govindaraj N, et al.

Environmental Science & Technology, 21(11), 1119-1123 (1987)

Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions.

Lemmetyinen H, et al.

Journal of Photochemistry, 30(3), 315-338 (1985)

Glucose as a clean and renewable reductant in the Pd-nanoparticle-catalyzed reductive homocoupling of bromo- and chloroarenes in water.

Antonio Monopoli et al.

The Journal of organic chemistry, 75(11), 3908-3911 (2010-05-14)

An efficient and highly sustainable Ullmann-type homocoupling of bromo- and chloroarenes, including the more challenging electron-rich chloroarenes (e.g., 4-chloroanisole), catalyzed by in situ generated Pd colloids, is carried out in aqueous medium under relatively mild conditions (temperatures ranging from 40

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全球贸易项目编号

货号	GTIN
159069-100G	04061838346315
159069-25G	04061838744364