159255
2,2′,4′-三氯苯乙酮
97%
别名:
2,4-二氯苯甲酰基甲基氯, 三氯苯乙酮
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关于此项目
线性分子式:
Cl2C6H3COCH2Cl
化学文摘社编号:
分子量:
223.48
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-218-2
Beilstein/REAXYS Number:
957098
MDL number:
产品名称
2,2′,4′-三氯苯乙酮, 97%
InChI key
VYWPPRLJNVHPEU-UHFFFAOYSA-N
InChI
1S/C8H5Cl3O/c9-4-8(12)6-2-1-5(10)3-7(6)11/h1-3H,4H2
SMILES string
ClCC(=O)c1ccc(Cl)cc1Cl
assay
97%
form
solid
bp
130-135 °C/4 mmHg (lit.)
mp
47-54 °C (lit.)
functional group
chloro
ketone
Quality Level
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General description
2,2′,4′-Trichloroacetophenone is an α-haloketone. It undergoes reduction to 2′,4′-dichloroacetophenone by glutathione-dependent cytosolic enzymes present in the liver, kidney and brain. It participates in the microwave induced N-alkylation of several azoles to afford the corresponding 1-(2′,4′-dichlorophenacyl)azoles.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Clean and efficient microwave-solvent-free synthesis of 1-(2', 4'-dichlorophenacyl) azoles.
Perez ER, et al.
Tetrahedron, 59(6), 865-870 (2003)
A Brundin et al.
Biochemical pharmacology, 31(23), 3885-3890 (1982-12-01)
alpha-Haloketones are highly reactive compounds, which are known to undergo enzymatic reduction to methyl ketones. The objective of this research was to characterize the enzymes involved in this reaction and to investigate the mechanism of the reaction. 2,2',4'-Trichloroacetophenone was reduced
Justin D Smith et al.
Nature communications, 10(1), 1837-1837 (2019-04-25)
Photocatalytic polymers offer an alternative to prevailing organometallics and nanomaterials, and they may benefit from polymer-mediated catalytic and material enhancements. MPC-1, a polymer photoredox catalyst reported herein, exhibits enhanced catalytic activity arising from charge transfer states (CTSs) between its two
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