160938
Resolve-Al EuFOD
99%, solid
别名:
Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕
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关于此项目
线性分子式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
化学文摘社编号:
分子量:
1037.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-616-1
MDL number:
产品名称
Resolve-Al EuFOD, 99%
Quality Level
assay
99%
form
solid
reaction suitability
core: erbium, reagent type: catalyst
mp
203-207 °C
SMILES string
CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F
InChI
1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;
InChI key
PTQJQBFRLLGICD-VNGPFPIXSA-K
General description
在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。
Application
当与 Resolve-Al AgFOD 结合使用时，可为芳香族化合物、铵盐以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。
Legal Information
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
相关内容
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 160938-100MG | 04061833278765 |
| 160938-1G | 04061838745811 |
| 160938-5G | 04061833498705 |