160938
Resolve-Al EuFOD
99%, solid
别名:
Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕
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关于此项目
线性分子式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
化学文摘社编号:
分子量:
1037.49
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
Resolve-Al EuFOD, 99%
质量水平
方案
99%
表单
solid
反应适用性
core: erbium
reagent type: catalyst
mp
203-207 °C
SMILES字符串
CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F
InChI
1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;
InChI key
PTQJQBFRLLGICD-VNGPFPIXSA-K
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一般描述
在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。
应用
当与 Resolve-Al AgFOD 结合使用时，可为芳香族化合物、铵盐以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。
法律信息
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
K D Schulze et al.
Biochimica et biophysica acta, 1467(1), 27-38 (2000-08-10)
Investigating the action of the fluorinated europium complex Eu(fod)3 on lipid membranes we found that the complex facilitates the ion transfer through the membrane. Electric measurements on planar lipid membranes showed that the membrane conductivity increases considerably by insertion of
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
Luminescent visualization of latent fingerprints by direct reaction with a lanthanide shift reagent.
J P Caldwell et al.
Journal of forensic sciences, 46(6), 1332-1341 (2001-11-21)
The utilization of the lanthanide shift reagent tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) europium (III) [Eu(fod)3] as a simple one-step reagent for the luminescent visualization of latent fingerprints has been investigated. UV excitation of Eu(fod)3-treated prints, achieved by using a hand-held UV lamp or
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