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Merck
CN

16120

Sigma-Aldrich

溴乙酰氯

≥95% (GC)

别名:

2-溴乙酰氯, 溴乙酰氯

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关于此项目

线性分子式:
BrCH2COCl
化学文摘社编号:
分子量:
157.39
Beilstein:
1209323
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

≥95% (GC)

折射率

n20/D 1.495

沸点

127-128 °C (lit.)

密度

1.89 g/mL at 20 °C

官能团

acyl chloride
bromo

储存温度

2-8°C

SMILES字符串

ClC(=O)CBr

InChI

1S/C2H2BrClO/c3-1-2(4)5/h1H2

InChI key

SYZRZLUNWVNNNV-UHFFFAOYSA-N

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一般描述

已经通过从头计算方法研究了溴乙酰氯的竞争性光离解。

应用

溴乙酰氯被用于合成α,α-二取代硫代异穆氏酮。它也用于制备1,3-二溴丙酮。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Cycloaddition chemistry of anhydro-4-hydroxy-1, 3-thiazolium hydroxides (thioisomunchnones) for the synthesis of heterocycles.
Padwa A, et al.
Synthesis, 1994(9), 993-1004 (1994)
Non-adiabatic effects in the photodissociation of bromoacetyl chloride.
Bacchus-Montabonel M-C, et al.
Chemical Physics Letters, 374(3), 307-313 (2003)
S S Husain et al.
The Biochemical journal, 108(5), 855-859 (1968-08-01)
Papain was irreversibly inhibited by 1,3-dibromoacetone, a reagent designed to react first with the active-site cysteine residue and subsequently with a second nucleophile. The molecular weight of the inhibited enzyme was indistinguishable from that of papain itself, and no evidence
Jonathan E Meegan et al.
Soft matter, 13(35), 5922-5932 (2017-08-05)
Four novel amino acid-functionalised triphenylenes have been prepared with glycine, l-alanine, l-phenylalanine and l-tryptophan ethyl ester side-chains. The glycine derivative is a good gelator of chloroform, the alanine derivative gels ethanol and toluene, and the phenylalanine derivative gels benzene and
Xueqi Sun et al.
International journal of biological macromolecules, 152, 349-358 (2020-02-23)
In this study, a new class of chitosan derivatives possessing sulfonium salts was synthesized, and characterized by FT-IR, 1H NMR, 13C NMR, and elemental analyses. IR spectra, 1H NMR and 13C NMR of the structural units of these polymers validated

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