161713
3,5-二甲氧基苯甲酰氯
97%
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关于此项目
线性分子式:
(CH3O)2C6H3COCl
化学文摘社编号:
分子量:
200.62
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-256-5
Beilstein/REAXYS Number:
511839
MDL number:
Assay:
97%
Form:
solid
产品名称
3,5-二甲氧基苯甲酰氯, 97%
InChI key
FTHPLWDYWAKYCY-UHFFFAOYSA-N
InChI
1S/C9H9ClO3/c1-12-7-3-6(9(10)11)4-8(5-7)13-2/h3-5H,1-2H3
SMILES string
COc1cc(OC)cc(c1)C(Cl)=O
assay
97%
form
solid
bp
157-158 °C/16 mmHg (lit.)
mp
43-46 °C (lit.)
functional group
acyl chloride
Quality Level
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General description
3,5-Dimethoxybenzoyl chloride undergoes addition reaction with 4,4-dimethyl-2-pentyne in presence of AlCl3 via 1,2- methyl shift.
Application
3,5-Dimethoxybenzoyl chloride was used to study the mechanism and kinetics of solvolysis of 3,4- and 3,5-dimethoxybenzoyl chlorides in various binary solvents.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Kinetic and Theoretical Consideration of 3, 4-and 3, 5-Dimethoxybenzoyl Chlorides Solvolyses.
Park K-H and Kevill DN.
Bull. Korean Chem. Soc., 34(10), 2989-2989 (2013)
Stereochemistry and mechanism of acylation of acetylenes.
Martens H, et al.
Tetrahedron, 31(2), 177-183 (1975)
Dongsheng Xu et al.
Journal of chromatography. A, 1593, 63-72 (2019-02-05)
An O-[2-(methacryloyloxy)-ethylcarbamoyl]-10,11-dihydroquinidine (MQD)-silica hybrid monolithic column was prepared by a facile "one-step" strategy within a 100 μm I.D. capillary. The influence of the methanol, ethylene glycol and water volume ratio, reaction temperature and time, cetyltrimethylammonium bromide and MQD monomers content
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