162884
3,4,7,8-四甲基-1,10-菲罗啉
≥98%
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关于此项目
经验公式（希尔记法）:
C16H16N2
化学文摘社编号:
分子量:
236.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
216-762-4
MDL number:
Assay:
≥98%
Form:
powder
InChI key
NPAXPTHCUCUHPT-UHFFFAOYSA-N
InChI
1S/C16H16N2/c1-9-7-17-15-13(11(9)3)5-6-14-12(4)10(2)8-18-16(14)15/h5-8H,1-4H3
SMILES string
Cc1cnc2c(ccc3c(C)c(C)cnc23)c1C
assay
≥98%
form
powder
reaction suitability
reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
mp
277-280 °C (lit.)
solubility
95% ethanol: soluble 50 mg/mL, clear to hazy, colorless to dark yellow
Quality Level
General description
3,4,7,8-四甲基-1,10-菲咯啉是一种金属螯合剂。作为配体并形成双核 Cu (II) 竹红菌乙素复合物。它还与锌形成四水合物（3,4,7,8-四甲基-1,10-菲咯啉-kappa2 N,N'）锌 (II) 硫代硫酸盐配合物。
Application
以 3,4,7,8-四甲基-1,10-菲咯啉为原料，合成了异相阳离子铱 (III) 配合物，3,4,7,8-四甲基-1,10-菲咯啉-双 [2-（2′,4′-二氟苯基）吡啶] 铱 (III) 六氟磷酸盐。
存储类别
11 - Combustible Solids
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Kristen E Funck et al.
Inorganic chemistry, 48(8), 3438-3452 (2009-04-14)
Pentanuclear cyanide-bridged clusters of the general formula {[M(tmphen)(2)](3)[M'(CN)(6)](2)} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) have been under investigation in our laboratories for a number of years. These related molecules are conveniently prepared by a building block approach that involves the reaction of mononuclear
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium (III) complex.
Bolink HJ, et al.
Journal of Materials Chemistry, 17(48), 5032-5041 (2007)
Actions of an inert nickel (II) chelate of tetramethyl-1,10-phenanthroline at calcium-dependent sites on the guinea-pig isolated atrium.
H J Grossman et al.
Methods and findings in experimental and clinical pharmacology, 1(4), 239-260 (1979-10-01)
Yi Sun et al.
Inorganic chemistry, 49(21), 10108-10116 (2010-09-30)
Five new dinuclear Cu(II) complexes were designed and synthesized, using hypocrellin B, a naturally occurring photosensitizer that has received extensive studies as promising photodynamic therapy (PDT) agent, as bridging ligand, and five kinds of diimine ligands, including 2,2'-bipyridine (bpy), 1,10-phenanthroline
M Enriqueta Díaz de Vivar et al.
Acta crystallographica. Section C, Crystal structure communications, 60(Pt 9), m451-m453 (2004-09-04)
In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising two N-atom donors from the tmph group and four aqua O-atom donors. The complex cation is connected to
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