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Merck
CN

16350

溴苯

≥99.5% (GC)

别名:

1-Bromobenzene, Bromobenzol, Monobromobenzene, Phenyl bromide

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关于此项目

经验公式（希尔记法）:
C6H5Br
化学文摘社编号:
108-86-1
分子量:
157.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57647528
EC Number:
203-623-8
Beilstein/REAXYS Number:
1236661
MDL number:
MFCD00000055

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产品名称

溴苯, ≥99.5% (GC)

InChI key

QARVLSVVCXYDNA-UHFFFAOYSA-N

InChI

1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H

SMILES string

Brc1ccccc1

vapor density

5.41 (vs air)

vapor pressure

10 mmHg ( 40 °C)

assay

≥99.5% (GC)

form

liquid

autoignition temp.

1051 °F

expl. lim.

36.5 %

refractive index

n20/D 1.559 (lit.)
n20/D 1.559

bp

156 °C (lit.)

mp

−31 °C (lit.)

solubility

alcohol: soluble 10.4g/100g at 25 °C
diethyl ether: soluble 71.3g/100g at 25 °C
water: insoluble 0.045g/100g at 30 °C (practically)
benzene: miscible
chloroform: miscible
hydrocarbons: miscible (petr.)

density

1.491 g/mL at 25 °C (lit.)

functional group

bromo

Quality Level

200

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相关类别

Application

溴苯被用于合成制备两亲性星形接枝共聚物所需的四臂星形链转移剂 。

Biochem/physiol Actions

溴苯通过形成反应性代谢产物芳香化重要的细胞大分子，诱导肝坏死 。

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

123.8 °F - closed cup

flash_point_c

51.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCM8940
BCCK2698
BCCH7377
BCCF7091
BCCC3505

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Star-like PAA-g-PPO well-defined amphiphilic graft copolymer synthesized by ATNRC and SET-NRC reaction.
Li Y, et al.
Journal of Polymer Science: Part A, General Papers, 48(10), 2084-2097 (2010)
Bromobenzene-induced liver necrosis. Protective role of glutathione and evidence for 3,4-bromobenzene oxide as the hepatotoxic metabolite.
D J Jollow et al.
Pharmacology, 11(3), 151-169 (1974-01-01)
Yuning Ma et al.
Environmental science & technology, 46(24), 13112-13117 (2012-11-28)
The 2,4,6-tribromophenoxy moiety is a common structural feature of several brominated flame retardants, and we have previously reported on the environmental concentrations of one such compound, 1,2-bis(2,4,6-tribromophenoxy) ethane (TBE). Here we report the atmospheric concentrations of TBE and three other
Verónica Guilarte et al.
Organic letters, 13(19), 5100-5103 (2011-09-03)
An efficient synthesis of thiophenes and benzo[b]thiophenes has been developed from easily available bromoenynes and o-alkynylbromobenzene derivatives. This novel one-pot procedure involves a Pd-catalyzed C-S bond formation using a hydrogen sulfide surrogate followed by a heterocyclization reaction. Moreover, in situ
Aiichiro Nagaki et al.
Chemical communications (Cambridge, England), 49(31), 3242-3244 (2013-03-15)
Reactions of functionalized aryllithiums with dialkyl oxalates were achieved using a flow microreactor to obtain α-keto esters with high selectivity by virtue of fast 1 : 1 micromixing.
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