16491
溴代丙酮酸甲酯
technical
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线性分子式:
BrCH2COCOOCH3
化学文摘社编号:
分子量:
180.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1754888
Assay:
≥95.0% (T)
Form:
liquid
InChI
1S/C4H5BrO3/c1-8-4(7)3(6)2-5/h2H2,1H3
SMILES string
COC(=O)C(=O)CBr
InChI key
MQONVZMIFQQQHA-UHFFFAOYSA-N
grade
technical
assay
≥95.0% (T)
form
liquid
density
1.70 g/mL at 20 °C (lit.)
functional group
bromo, ester, ketone
storage temp.
2-8°C
Quality Level
General description
溴丙酮酸甲酯是一种碳酸酐酶抑制剂。
Application
溴丙酮酸甲酯用于合成2-（4-氨基-4-羧基丁基）噻唑-4-羧酸和甲基-1-（溴甲基）-2，3，4，9-四氢-1H-吡啶并[3，4-b]吲哚-1-羧酸酯。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
257.0 °F - closed cup
flash_point_c
125 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Anne Katrine Kehler et al.
Investigative ophthalmology & visual science, 48(10), 4688-4693 (2007-09-28)
Inhibition of carbonic anhydrase in the eye is an important treatment modality for reducing the intraocular pressure in glaucoma. However, evidence suggests that carbonic anhydrase inhibition also exerts a relaxing effect on the vessels in the optic nerve, and it
Further degradation products of cephalosporin C. Isolation and synthesis of 2-(4-amino-4-carboxybutyl)thiazole-4-carboxylic acid.
J D JEFFERY et al.
The Biochemical journal, 75, 216-223 (1960-05-01)
Pinhong Chen et al.
The Journal of organic chemistry, 74(19), 7533-7535 (2009-09-26)
With chemoselective Dieckmann condensation as the key step, the protective-group-free total synthesis of (+/-)-subincanadine F was accomplished in 7 steps from the commercially available tryptamine in 33% overall yield.
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