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167304

碘丁烷

Name: 碘丁烷
Brand: ALDRICH

99%, contains copper as stabilizer

别名:

丁基碘

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关于此项目

线性分子式:

CH₃(CH₂)₃I

化学文摘社编号:

542-69-8

分子量:

184.02

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850205

MDL number:

MFCD00001098

Beilstein/REAXYS Number:

1420755

Assay:

99%

Form:

liquid

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属性

vapor density

~5 (vs air)

Quality Level

100

assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.498 (lit.)

bp

130-131 °C (lit.)

mp

−103 °C (lit.)

solubility

alcohol: soluble, diethyl ether: soluble, water: insoluble

density

1.617 g/mL at 25 °C (lit.)

functional group

alkyl halide, iodo

SMILES string

CCCCI

InChI

1S/C4H9I/c1-2-3-4-5/h2-4H2,1H3

InChI key

KMGBZBJJOKUPIA-UHFFFAOYSA-N

说明

General description

通过程序升温脱附和反射-吸收红外光谱研究了1-碘丁烷在洁净、含氢和氘Pt(111)单晶表面的热化学。.

1-碘丁烷是一种烷基卤化物，在SN²亲核反应中用作亲电体。

Application

1-碘丁烷用于合成：

S -烷基化 5-（2-,3-和 4-甲氧基苯基）-4 H -1,2,4-三唑-3-硫醇
5-（2-,3-和 4-甲氧基苯基）-4-苯基-4 H -1,2,4-三唑-3-硫醇
在乙酸乙酯中与 1-甲基吡咯烷反应的 N -丁基- N -甲基吡咯并双（三氟甲磺酰基）酰亚胺

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pictograms

GHS02,GHS06

signalword

Danger

hcodes

H226,H331

pcodes

P210 - P233 - P240 - P241 - P242 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Inhalation - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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NMR Kinetics of the SN2 Reaction between BuBr and I--: An Introductory Organic Chemistry Laboratory Exercise

Mobley, T Andrew

Journal of Chemical Education, 92, 534-537 (2015)

Synthesis of 5-(2-,3- and 4-methoxyphenyl)-4H-1,2,4-triazole-3-thiol derivatives exhibiting anti-inflammatory activity.

L Labanauskas et al.

Farmaco (Societa chimica italiana : 1989), 59(4), 255-259 (2004-04-15)

New S-alkylated 5-(2-,3- and 4-methoxyphenyl)-4H-1,2,4-triazole-3-thiols (5a-c, 6a-c) and 5-(2-,3- and 4-methoxyphenyl)-4-phenyl-4H-1,2,4-triazole-3-thiols (7a-c, 8a-c, 9a-c) were synthesized by the alkylation of 3-(2-,3- and 4-methoxyphenyl)-4,5-dihydro-1H-1,2,4-triazole-5-thiones (3a-c) or 3-(2-,3- and 4-methoxyphenyl)-4-phenyl-4,5-dihydro-1H-1,2,4-triazole-5-thiones (4a-c) with 1-iodobutane or 1-(1,3-benzodioxol-5-yl)-2-bromo-1-ethanone, 2-bromo-1-(2,3-dihydro-1,4-benzodioxin-6-yl)-1-ethanone and 2-bromo-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-1-ethanone. Compounds 3a-c and 4a-c

Formation of 1-[123I]iodobutane in labeling [123I]iomazenil by iododestannylation: implications for the reaction mechanism.

Y Zea-Ponce et al.

Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 45(1), 63-68 (1994-01-01)

The benzodiazepine receptor tracer [123I]iomazenil (Ro 16-0154, IMZ) can be prepared in close to theoretical specific activity by the reaction of its tributyltin precursor (IMZ-SnBu3) with [123I]NaI in the presence of Iodogen. However, the labeling reaction is associated with variably

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全球贸易项目编号

货号	GTIN
167304-100G	04061838749505
167304-500G	04061838749512
167304-5G	04061838749529