167940
巴豆酸乙酯
99%
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关于此项目
线性分子式:
CH3CH=CHCOOC2H5
分子量:
114.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-808-7
Beilstein/REAXYS Number:
635834
MDL number:
Assay:
99%
Form:
liquid
InChI key
ZFDIRQKJPRINOQ-HWKANZROSA-N
InChI
1S/C6H10O2/c1-3-5-6(7)8-4-2/h3,5H,4H2,1-2H3/b5-3+
SMILES string
CCOC(=O)\C=C\C
vapor density
3.9 (vs air)
assay
99%
form
liquid
refractive index
n20/D 1.424 (lit.)
bp
142-143 °C (lit.)
density
0.918 g/mL at 25 °C (lit.)
functional group
ester
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General description
巴豆酸乙酯在硼氢化作用下生成 2-氚化 3-羟基丁酸 。
Application
巴豆酸乙酯用于 (+/-)-蝙蝠葛酸的全合成 。它也被用于 3-甲基-4-氧代辛酸乙酯的合成 。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
35.6 °F - closed cup
flash_point_c
2 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of all stereoisomers of cognac lactones via microbial reduction and enzymatic resolution strategies.
Benedetti F, et al.
Tetrahedron Asymmetry, 12(3), 505-511 (2001)
P Willadsen et al.
European journal of biochemistry, 54(1), 247-252 (1975-05-01)
1. A specimen of stereospecifically 2-tritiated 3-hydroxybutyric acid was prepared by hydroboration of ethyl crotonate. It was assumed that the hydroboration reaction took a syn course and hence that (2R,3S) plus (2S,3R)-3-hydroxy[2 minus 3H1]butyric acid was formed after oxidation and
Hongjuan Hu et al.
The Journal of organic chemistry, 69(11), 3782-3786 (2004-05-22)
A modular and concise total synthesis of (+/-)-daurichromenic acid has been accomplished in four steps from ethyl acetoacetate, ethyl crotonate, and trans,trans-farnesal. A series of analogues of this natural product, which has potent anti-HIV activity, were also prepared from ethyl
Amélie Slegers et al.
Molecules (Basel, Switzerland), 20(6), 10980-11016 (2015-06-18)
Developed from crosses between Vitis vinifera and North American Vitis species, interspecific hybrid grape varieties are becoming economically significant in northern areas, where they are now extensively grown for wine production. However, the varietal differences between interspecific hybrids are not
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