168521
Luperox® DI，叔-丁基过氧化物
98%
别名:
叔丁基过氧化物, 二叔丁基过氧化物
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关于此项目
线性分子式:
(CH3)3COOC(CH3)3
化学文摘社编号:
分子量:
146.23
Beilstein:
1735581
EC 号:
MDL编号:
UNSPSC代码:
12352120
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
40 mmHg ( 20 °C)
质量水平
方案
98%
表单
liquid
反应适用性
reagent type: oxidant
折射率
n20/D 1.3891 (lit.)
沸点
109-110 °C (lit.)
密度
0.796 g/mL at 25 °C (lit.)
官能团
peroxide
储存温度
2-8°C
SMILES字符串
CC(C)(C)OOC(C)(C)C
InChI
1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3
InChI key
LSXWFXONGKSEMY-UHFFFAOYSA-N
应用
Luperox® DI，叔-丁基过氧化物已用作自由基引发剂，以诱导自由基聚合。它还被用作十六烷增强剂，研究确定羧酸盐为基础的扩展表面活性剂反胶团微乳与乙醇和植物油/柴油混合物的相行为。
法律信息
Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Flam. Liq. 2 - Muta. 2 - Org. Perox. E
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 1
闪点(°F)
42.8 °F - closed cup
闪点(°C)
6 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Hironori Kitaguchi et al.
Journal of the American Chemical Society, 127(18), 6605-6609 (2005-05-05)
Well-resolved ESR spectra of free pentadienyl radicals have been observed under photoirradiation of di-tert-butylperoxide (Bu(t)OOBu(t)) and polyunsaturated fatty acids in the absence of O(2), allowing us to determine the hfc values. The hfc values of linoleyl radical indicate that the
Carson T Riche et al.
Nature communications, 7, 10780-10780 (2016-02-24)
The translation of batch chemistries onto continuous flow platforms requires addressing the issues of consistent fluidic behaviour, channel fouling and high-throughput processing. Droplet microfluidic technologies reduce channel fouling and provide an improved level of control over heat and mass transfer
B H Shen et al.
Science advances, 5(7), eaaw4856-eaaw4856 (2019-07-25)
Electrochemical reduction of lithium ion battery electrolyte on Si anodes was mitigated by synthesizing nanoscale, conformal polymer films as artificial solid electrolyte interface (SEI) layers. Initiated chemical vapor deposition (iCVD) was used to deposit poly(1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane) (pV4D4) onto silicon thin film
Vegetable oil-based microemulsions using carboxylate-based extended surfactants and their potential as an alternative renewable biofuel.
Attaphong C
Fuel: The Science and Technology of Fuel and Energy, 94, 606-613 (2012)
A Mortensen et al.
FEBS letters, 426(3), 392-396 (1998-05-26)
Peroxyl radicals, as model for peroxyl radicals formed during autoxidation of lipids, have been generated in three solvent systems (cyclohexane, tetrahydrofuran and tert-butanol/water) by steady-state and laser flash photolysis, and their reaction with beta-carotene studied. Steady-state photolysis experiments showed that
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