169021
二苯二硫醚
99%
别名:
NSC 2689, 二硫化二苯
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线性分子式:
C6H5SSC6H5
化学文摘社编号:
分子量:
218.34
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-926-4
Beilstein/REAXYS Number:
639794
MDL number:
产品名称
二苯二硫醚, 99%
InChI key
GUUVPOWQJOLRAS-UHFFFAOYSA-N
InChI
1S/C12H10S2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
SMILES string
S(Sc1ccccc1)c2ccccc2
assay
99%
form
powder
mp
58-60 °C (lit.)
solubility
xylene: soluble 3%, clear, colorless to yellow
functional group
disulfide
Quality Level
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Application
苯基二硫化物是 dyfonate（杀虫剂）的水解产物 。苯基二硫化物（二苯基二硫化物）通过胺介导的单电子转移机制参与炔烃的加氢硫醚化反应 。
General description
二苯二硫醚被用作合成苯基硒硫化物（PhS-SePh）的前体，而PhS-SePh在锂离子电池的生产中起着重要的作用。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Identification of hydrolytic metabolites of dyfonate in alkaline aqueous solutions by using high performance liquid chromatography-UV detection and gas chromatography-mass spectrometry.
Wang T, et al.
International Journal of Environmental Analytical Chemistry, 90(12), 948-961 (2010)
Mixture is better: enhanced electrochemical performance of phenyl selenosulfide in rechargeable lithium batteries
Guo, Wei and Bhargav
Journal of the Chemical Society. Chemical Communications, 54, 8873-8876 (2018)
Y K Nakamura et al.
Mutation research, 385(1), 41-46 (1997-12-31)
S-Methyl methanethiosulfonate (MMTS) and diphenyl disulfide (DPDS) are temporary enzyme-sulfhydryl blocking agents. They are naturally occurring phytoalexin-like and synthetic substances known to be very potent bio-antimutagens in Escherichia coli B/r WP2. In the present paper, the suppressing effects of MMTS
Tsuyoshi Taniguchi et al.
Organic letters, 11(15), 3298-3301 (2009-09-02)
Hydrothiolation of alkynes proceeds with diphenyl disulfide and tripropylamine. Amine-mediated single electron transfer to diphenyl disulfide can be proposed for the reaction mechanism. Applications of the method to radical cyclizations of eneyne compounds are also presented.
J M Young et al.
Agents and actions, 21(3-4), 314-315 (1987-08-01)
Indomethacin was administered subcutaneously to rats, 4 mg/kg/day for 4 consecutive days in order to produce erosions of the small intestine which were scored at necropsy on day 5. Orally administered phenidone (up to 250 mg/kg/day), a mixed cycloocygenase-lipoxygenase inhibitor
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