17324
四(五氟苯基)硼酸锂乙醚共聚物
别名:
Tetrakis(pentafluorophenyl)boron lithium ethyl etherate
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关于此项目
经验公式（希尔记法）:
C24BF20Li · 2.5C4H10O
化学文摘社编号:
分子量:
871.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
reaction suitability
core: boron, reagent type: catalyst
mp
117-122 °C
SMILES string
[Li+].CCOCC.Fc1c(F)c(F)c(c(F)c1F)[B-](c2c(F)c(F)c(F)c(F)c2F)(c3c(F)c(F)c(F)c(F)c3F)c4c(F)c(F)c(F)c(F)c4F
InChI
1S/C24BF20.C4H10O.Li/c26-5-1(6(27)14(35)21(42)13(5)34)25(2-7(28)15(36)22(43)16(37)8(2)29,3-9(30)17(38)23(44)18(39)10(3)31)4-11(32)19(40)24(45)20(41)12(4)33;1-3-5-4-2;/h;3-4H2,1-2H3;/q-1;;+1
InChI key
KPLZKJQZPFREPG-UHFFFAOYSA-N
Application
四（五氟苯基）硼酸锂乙醚可用作：
- 电化学反应中与过渡金属催化剂配位的反离子，以增强其酸度或溶解度。
- 拜耳-维利格环烷酮氧化反应中的催化剂，以在双氧水和草酸存在下获得内酯。
- 合成聚（降冰片烯酯）的活化剂。
Packaging
无底玻璃瓶。内含物装在插入式熔锥内。
Other Notes
用于生成阳离子过渡金属络合物的盐
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation.
B V Mork et al.
Journal of the American Chemical Society, 123(39), 9702-9703 (2001-09-27)
H. Shen, R.F. Jordan
Organometallics, 22, 1878-1878 (2003)
Synthesis of poly (norbornene ester) s by using ($\eta$ 3-substituted allyl) palladium (NHC) complex as catalyst and investigation of their chemical structure-Glass transition temperature-Refractive index relationships
Lee DH, et al.
Fibers and Polymers, 18(8), 1438-1444 (2017)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 17324-100MG | 04061833278772 |