17457
α-溴异丁酸甲酯
≥99.0% (GC)
别名:
2-溴-2-甲基丙酸甲酯
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关于此项目
线性分子式:
(CH3)2CBrCOOCH3
化学文摘社编号:
分子量:
181.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
245-657-6
Beilstein/REAXYS Number:
1209484
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
Quality Level
assay
≥99.0% (GC)
form
liquid
density
1.399 g/mL at 20 °C (lit.)
functional group
bromo, ester
SMILES string
COC(=O)C(C)(C)Br
InChI
1S/C5H9BrO2/c1-5(2,6)4(7)8-3/h1-3H3
InChI key
PQUSVJVVRXWKDG-UHFFFAOYSA-N
Application
甲基 α-在 Reformatsky反应中使用了溴异丁酸盐，以制备 1,4-二取代 3,3-二甲基氮杂环丁烷-2-酮 。
可生成带有甲基末端基团的聚合物的原子转移自由基聚合 (ATRP) 引发剂
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
120.2 °F - closed cup
flash_point_c
49 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
实验方案
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
Reformatsky reaction of methyl ?-bromoisobutyrate with Schiff bases derived from salicylaldehyde and 2-hydroxynaphthalene-1-carbaldehyde.
Russ. J. Org. Chem., 40(6), 834-836 (2004)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| CDS007440-5MG | 04061828988105 |
| 17457-100ML | 04061838752024 |