177199
甲基炔丙基醚
≥97%
别名:
3-甲氧基-1-丙炔, 甲基 2-丙炔基醚
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关于此项目
线性分子式:
HC≡CCH2OCH3
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-998-1
Beilstein/REAXYS Number:
878166
MDL number:
产品名称
甲基炔丙基醚, ≥97%
InChI key
YACFFSVYSPMSGS-UHFFFAOYSA-N
InChI
1S/C4H6O/c1-3-4-5-2/h1H,4H2,2H3
SMILES string
COCC#C
assay
≥97%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
61-62 °C (lit.)
density
0.83 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
Quality Level
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Application
甲基炔丙基醚用于合成[Ru3(μ3-κ(2)-HNNMe2)(μ3-κ(2)-MeOCH2CCH2)(μ-CO)2(CO)6]。
General description
目前已研究了甲基炔丙基醚的拉曼光谱。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Javier A Cabeza et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(20), 6040-6052 (2005-07-30)
The reactions of the hydrido-triruthenium cluster complex [Ru3(mu-H)(mu3-kappa(2)-HNNMe2)(CO)9] (1; H2NNMe2 = 1,1-dimethylhydrazine) with alkynes that have alpha-hydrogen atoms give trinuclear derivatives containing edge-bridging allyl or face-capping alkenyl ligands. Under mild conditions (THF, 70 degrees C) the isolated products are as
Conformational stability, barriers to internal rotation, ab initio calculations and vibrational assignment of methyl propargyl ether.
Journal of Molecular Structure, 320, 193-216 (1994)
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