DPPF

Name: DPPF
Brand: ALDRICH

97%, powder

别名:

1,1′-二茂铁二基-双(二苯基膦), dppf

登录查看组织和合同定价。

选择尺寸

关于此项目

经验公式（希尔记法）:

C₃₄H₂₈FeP₂

化学文摘社编号:

12150-46-8

分子量:

554.38

UNSPSC Code:

12350000

PubChem Substance ID:

24850625

NACRES:

NA.22

MDL number:

MFCD00001422

主要文件

查看所有文档

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

产品名称

DPPF, 97%

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

InChI key

HPXNTHKXCYMIJL-UHFFFAOYSA-N

assay

97%

form

powder

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Ene Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Tsuji-Trost Reaction

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

181-182 °C (dec.) (lit.)

functional group

phosphine

greener alternative category

Aligned,

Quality Level

200

正在寻找类似产品? 访问产品对比指南

Application

Pd(II)-催化交叉偶联合成奥氮平环系统的配体。

可作为从胺和酒精绿色合成胺的钌催化借氢反应的配体。

借氢反应法钌催化胺和磺酰胺N-烷基化

General description

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处了解更多详情。

通过Pd-膦依序形成C-C和C-O键，制备新型官能化呋喃衍生物。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

SHBS8940

0000424006

0000398133

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Anastasia, L.; Dumond, Y. R.; Negishi, E.

European Journal of Organic Chemistry, 3039-3039 (2001)

Wolfe, J. P.; Buchwald, S. L.

Journal of the American Chemical Society, 119, 6054-6054 (1997)

Stereoselective ring opening of meso bicyclic hydrazines: a straightforward approach to hydrazino cyclopentenic cores.

Alejandro Pérez Luna et al.

Organic letters, 5(25), 4771-4774 (2003-12-05)

The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed allylic substitution reaction. In the latter case, enantioenriched compounds with ee values up to

Tanimori, Shinji; et al.

Synthesis, 5, 865-869 (2006)

A new one-Pot synthesis of alkynylphosphonates

Lera et al.

Organic letters, 2(24), 3873-3875 (2000-12-02)

A method for the palladium-catalyzed synthesis of alkynylphosphonates from 1,1-dibromo-1-alkenes has been developed. In general, the best catalyst system for this transformation was found to be Pd(OAc)(2), dppf, H-phosphonate, propylene oxide, DMF, 80 degrees C. The reaction appears tolerant of

查看所有相关文献

DPPF

97%, powder

选择尺寸

关于此项目

主要文件

属性

产品名称

SMILES string

InChI

InChI key

assay

form

reaction suitability

greener alternative product characteristics

sustainability

mp

functional group

greener alternative category

Quality Level

相关类别

说明

Application

General description

安全信息

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

已有该产品？

同行评审论文

技术文章和实验方案

相关内容

技术服务