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178098

戊二酰亚胺

Name: 戊二酰亚胺
Brand: ALDRICH

98%

别名:

2,6-Piperidinedione, NSC 58190

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关于此项目

经验公式（希尔记法）:

C₅H₇NO₂

化学文摘社编号:

1121-89-7

分子量:

113.11

NACRES:

NA.22

PubChem Substance ID:

24850719

UNSPSC Code:

12352100

EC Number:

214-340-4

MDL number:

MFCD00006670

Assay:

98%

Form:

solid

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属性

Quality Level

200

assay

98%

form

solid

mp

155-157 °C (lit.)

SMILES string

O=C1CCCC(=O)N1

InChI

1S/C5H7NO2/c7-4-2-1-3-5(8)6-4/h1-3H2,(H,6,7,8)

InChI key

KNCYXPMJDCCGSJ-UHFFFAOYSA-N

说明

General description

A glutarimide antibiotic, 9-methylstreptimidone, shows antiviral, antitumor and antifungal activities.

Application

Reactant for:
Thionations
Biocatalytic asymmetric synthesis of chiral amines from ketones applied to sitagliptin manufacture
Synthesis of β-adrenoceptor ligands
Enantioselective synthesis of securinega alkaloids
Intramolecular amidocyclopropanation reactions
Synthesis of alpha-fluoro-alpha amino amides

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Biosynthesis of 9-methylstreptimidone involves a new decarboxylative step for polyketide terminal diene formation.

Bo Wang et al.

Organic letters, 15(6), 1278-1281 (2013-02-27)

9-Methylstreptimidone is a glutarimide antibiotic showing antiviral, antifungal, and antitumor activities. Genome scanning, bioinformatics analysis, and gene inactivation experiments reveal a gene cluster responsible for the biosynthesis of 9-methylstreptimidone in Streptomyces himastatinicus. The unveiled machinery features both acyltransferase- and thioesterase-less

Iso-migrastatin congeners from Streptomyces platensis and generation of a glutarimide polyketide library featuring the dorrigocin, lactimidomycin, migrastatin, and NK30424 scaffolds.

Jianhua Ju et al.

Journal of the American Chemical Society, 127(34), 11930-11931 (2005-08-25)

Iso-Migrastatin (10) has been shown to be the main natural product of Streptomyces platensis, which undergoes a facile, H2O-mediated rearrangement into dorrigocin A (2), 13-epi-dorrigocin A (11), dorrigocin B (3), and migrastatin (1). Eight new congeners (12-19) of 10 were

Synthesis of cyclic imides from simple diols.

Jian Zhang et al.

Angewandte Chemie (International ed. in English), 49(36), 6391-6395 (2010-07-28)

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全球贸易项目编号

货号	GTIN
178098-25G	04061833544860
178098-5G	04061833320365