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经验公式(希尔记法):
C16H30B2
化学文摘社编号:
分子量:
244.03
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
605509
Form:
solid
InChI
1S/C16H28B2/c1-5-13-7-2-8-14(6-1)17(13)18-15-9-3-10-16(18)12-4-11-15/h13-16H,1-12H2/t13-,14+,15-,16+
SMILES string
C1C[C@H]2CCC[C@@H](C1)B2B3[C@H]4CCC[C@@H]3CCC4
InChI key
IYDIZBOKVLHCQZ-GEEKYZPCSA-N
form
solid
reaction suitability
reagent type: reductant
mp
150-152 °C (lit.)
Quality Level
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Application
已发现将过氧酯还原为醇(不伴随过氧键还原)的试剂。
用于炔烃、腈类、和酮类的硼氢化反应。
空气稳定的结晶试剂,用于将环状缩醛和缩酮还原裂解为单苄化 1,2-二醇。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hong-Xia Jin et al.
The Journal of organic chemistry, 70(11), 4240-4247 (2005-05-21)
Reduction of organic molecules that contain a peroxy bond is broadly considered as a "risky" and uncertain operation when cleavage of the peroxy linkage is not desired. For this reason, such reduction steps are normally avoided at the planning stage
Synlett, 349-349 (1991)
Tetrahedron Letters, 32, 6239-6239 (1991)
Chemische Berichte, 126, 285-285 (1993)
Organic Process Research & Development, 10, 1076-1076 (2006)
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