178721
碘苯二乙酸
98%
别名:
二乙酸亚碘酰苯, 碘苯二乙酸酯
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关于此项目
线性分子式:
C6H5I(O2CCH3)2
化学文摘社编号:
分子量:
322.10
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-808-1
Beilstein/REAXYS Number:
1879369
MDL number:
assay
98%
form
powder
reaction suitability
reagent type: catalyst, reagent type: oxidant
reaction type: C-H Activation
mp
161-163 °C (lit.)
functional group
iodo
SMILES string
CC(OI(OC(C)=O)C1=CC=CC=C1)=O
InChI
1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
InChI key
ZBIKORITPGTTGI-UHFFFAOYSA-N
Application
橙花醇转化为橙花醛的 TEMPO 氧化反应中的化学计量氧化剂。用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。
用于合成各种杂环化合物的试剂。
用于室温下钯催化的吲哚的 2-芳基化反应。
肟和吡啶底物的未活化sp3 C-H键与PhI(OAc)2作为化学计量氧化剂进行高度区域选择性和化学选择性Pd(II)催化氧化。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
商品
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
Bikash Dangi et al.
Chembiochem : a European journal of chemical biology, 19(21), 2273-2282 (2018-08-24)
CYP154C8 catalyzes the hydroxylation of diverse steroids, as has previously been demonstrated, by using an NADH-dependent system including putidaredoxin and putidaredoxin reductase as redox partner proteins carrying electrons from NADH. In other reactions, CYP154C8 reconstituted with spinach ferredoxin and NADPH-dependent
Jayasree Seayad et al.
Organic letters, 12(7), 1412-1415 (2010-03-13)
Copper(I) or -(II) salts with weakly coordinating anions catalyze the diacetoxylation of olefins efficiently in the presence of PhI(OAc)(2) as the oxidant under mild conditions. The reaction is effective for aryl, aryl alkyl, as well as aliphatic terminal and internal
Synlett, 221-221 (1994)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 178721-1KG | 04061826714447 |
| 178721-5G | 04061838753908 |
| 178721-100G | 04061838753885 |
| 178721-25G | 04061838753892 |