183342
苯基氯化硒
98%
别名:
苯基硒氯, 苯硒酰氯
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关于此项目
线性分子式:
C6H5SeCl
化学文摘社编号:
分子量:
191.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
227-196-2
Beilstein/REAXYS Number:
1237091
MDL number:
产品名称
苯基氯化硒, 98%
InChI key
WJCXADMLESSGRI-UHFFFAOYSA-N
InChI
1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
SMILES string
Cl[Se]c1ccccc1
assay
98%
form
solid
bp
120 °C/20 mmHg (lit.)
mp
59-62 °C (lit.)
Quality Level
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Application
苯基硒酰氯用于合成（环丁基-1-烯基硒酰）苯 。
General description
苯基硒酰氯是 2-氨基醇的合成子。它是有机合成中的一种通用试剂。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Inorganic Chemistry, 30, 3402-3402 (1991)
Tetrahedron, 47, 4211-4211 (1991)
Le-Ping Liu et al.
The Journal of organic chemistry, 69(8), 2805-2808 (2004-04-13)
The reaction of methylenecyclopropanes 1 with phenylsulfenyl chloride or phenylselenyl chloride gives (cyclobut-1-enylsulfanyl)benzene or (cyclobut-1-enylselanyl)benzene along with ring-opened product in good total yields at 0 degrees C in various solvents. A plausible mechanism has been proposed.
The Journal of Organic Chemistry, 58, 3355-3355 (1993)
Tetrahedron, 49, 1841-1841 (1993)
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