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关于此项目
经验公式(希尔记法):
C10H7Br
化学文摘社编号:
分子量:
207.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-452-5
Beilstein/REAXYS Number:
1858110
MDL number:
产品名称
2-溴萘, 97%
InChI key
APSMUYYLXZULMS-UHFFFAOYSA-N
InChI
1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
SMILES string
Brc1ccc2ccccc2c1
assay
97%
form
solid
impurities
≤3% 1-bromonaphthalene
bp
281-282 °C (lit.)
mp
52-55 °C (lit.)
solubility
methanol: soluble 50 mg/mL, clear, colorless to yellow
functional group
bromo
Quality Level
Gene Information
human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)
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Application
在微波辐射下,2-溴萘在水中通过Suzuki交叉偶联反应可用于合成联芳。
General description
2-溴萘与氰化亚铜在 N-甲基吡咯烷酮中的反应已有研究。 2-溴萘在甲醇溶剂中的T1→Tn转变的纳秒时间分辨共振拉曼光谱已有研究。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Rapid microwave-promoted Suzuki cross coupling reaction in water.
Bai L, et al.
Green Chemistry, 5(5), 615-617 (2003)
Nanosecond time-resolved resonance Raman investigation of the T1→ Tn transition of 2-bromonaphthalene.
Shoute LCT, et al.
Chemical Physics Letters, 290(1), 24-28 (1998)
Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.
Sheehan J, et al.
The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)
Isaiah R Speight et al.
Molecules (Basel, Switzerland), 25(3) (2020-02-06)
Owing to the strength of the C-F bond, the 'direct' preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods
J M Shoulder et al.
SAR and QSAR in environmental research, 30(4), 229-245 (2019-03-22)
Persistent organic contaminants in the environment pose an environmental risk due to widespread occurrence and toxic properties. Advanced oxidation processes (AOPs) are treatment methods that have been used to successfully degrade organic contaminants in water, soil, sediments and sludge. Reaction
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