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Merck
CN

183644

2-溴萘

97%

别名:

β-溴萘, β-萘基溴, 2-萘基溴

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关于此项目

经验公式(希尔记法):
C10H7Br
化学文摘社编号:
分子量:
207.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-452-5
Beilstein/REAXYS Number:
1858110
MDL number:
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产品名称

2-溴萘, 97%

InChI key

APSMUYYLXZULMS-UHFFFAOYSA-N

InChI

1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H

SMILES string

Brc1ccc2ccccc2c1

assay

97%

form

solid

impurities

≤3% 1-bromonaphthalene

bp

281-282 °C (lit.)

mp

52-55 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear, colorless to yellow

functional group

bromo

Quality Level

Gene Information

human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)

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Application

在微波辐射下,2-溴萘在水中通过Suzuki交叉偶联反应可用于合成联芳

General description

2-溴萘与氰化亚铜在 N-甲基吡咯烷酮中的反应已有研究。 2-溴萘在甲醇溶剂中的T1→Tn转变的纳秒时间分辨共振拉曼光谱已有研究

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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Rapid microwave-promoted Suzuki cross coupling reaction in water.
Bai L, et al.
Green Chemistry, 5(5), 615-617 (2003)
Nanosecond time-resolved resonance Raman investigation of the T1→ Tn transition of 2-bromonaphthalene.
Shoute LCT, et al.
Chemical Physics Letters, 290(1), 24-28 (1998)
Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.
Sheehan J, et al.
The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)
Isaiah R Speight et al.
Molecules (Basel, Switzerland), 25(3) (2020-02-06)
Owing to the strength of the C-F bond, the 'direct' preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods
J M Shoulder et al.
SAR and QSAR in environmental research, 30(4), 229-245 (2019-03-22)
Persistent organic contaminants in the environment pose an environmental risk due to widespread occurrence and toxic properties. Advanced oxidation processes (AOPs) are treatment methods that have been used to successfully degrade organic contaminants in water, soil, sediments and sludge. Reaction

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