183660
3,3,-二甲基丙烯酰氯
97%, contains 400 ppm phenothiazine as inhibitor
别名:
3-甲基-2-丁烯酰氯, 3-甲基巴豆酰氯, 异戊烯酰氯
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线性分子式:
(CH3)2C=CHCOCl
化学文摘社编号:
分子量:
118.56
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
222-109-4
Beilstein/REAXYS Number:
1560268
MDL number:
Assay:
97%
Form:
liquid
产品名称
3,3,-二甲基丙烯酰氯, 97%, contains 400 ppm phenothiazine as inhibitor
InChI key
BDUBTLFQHNYXPC-UHFFFAOYSA-N
InChI
1S/C5H7ClO/c1-4(2)3-5(6)7/h3H,1-2H3
SMILES string
C\C(C)=C\C(Cl)=O
assay
97%
form
liquid
contains
400 ppm phenothiazine as inhibitor
refractive index
n20/D 1.476 (lit.)
bp
145-147 °C (lit.)
density
1.065 g/mL at 25 °C (lit.)
functional group
acyl chloride
Quality Level
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Application
3,3-Dimethylacryloyl chloride was used in the synthesis of:
- substituted 4,4-dimethyl-3,4-dihydro-1H-quinolin-2-one via condensation with aniline
- N-(3,3-Dimethylacryloyl)-(S)-leucine methyl ester
General description
3,3-Dimethylacryloyl chloride reacts with silylketene acetals in acetonitrile to give δ-ethylenic β-keto esters.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
123.8 °F - closed cup
flash_point_c
51 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Marie-Anne Letellier et al.
European journal of medicinal chemistry, 43(8), 1730-1736 (2008-01-01)
A new series of substituted 4,4-dimethyl-3,4-dihydro-1H-quinolin-2-one have been prepared via condensation of 3,3-dimethylacryloyl chloride with aniline. Details of synthetic procedures are shown. Our aim was to investigate the potency of our original heterocycle in the inhibition of the Rho-kinase enzyme
Reaction of silylketene acetals with 3, 3-dimethylacryloyl chloride.
Rousseau G and Blanco L.
Tetrahedron Letters, 26(35), 4195-4196 (1985)
Structure and Biosynthesis of Chrysophysarin A, a Plasmodial Pigment from the Slime Mould Physarum polycephalum (Myxomycetes).
Eisenbarth S and Steffan B.
Tetrahedron, 56(3), 363-365 (2000)
Vishal Nanavaty et al.
Molecular cell, 78(4), 752-764 (2020-04-26)
Dysregulation of DNA methylation and mRNA alternative cleavage and polyadenylation (APA) are both prevalent in cancer and have been studied as independent processes. We discovered a DNA methylation-regulated APA mechanism when we compared genome-wide DNA methylation and polyadenylation site usage
Seon-Mi Seo et al.
Pesticide biochemistry and physiology, 113, 55-61 (2014-07-24)
This study investigated the fumigant toxicity of 4 Asteraceae plant essential oils and their constituents against the Japanese termite Reticulitermes speratus Kolbe. Fumigant toxicity varied with plant essential oils or constituents, exposure time, and concentration. Among the tested essential oils
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