183695
2′-溴苯乙酮
99%
别名:
1-乙酰基-2-溴苯
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关于此项目
线性分子式:
BrC6H4COCH3
化学文摘社编号:
分子量:
199.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-398-1
Beilstein/REAXYS Number:
1931534
MDL number:
Assay:
99%
Form:
liquid
InChI key
PIMNFNXBTGPCIL-UHFFFAOYSA-N
InChI
1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
SMILES string
CC(=O)c1ccccc1Br
assay
99%
form
liquid
refractive index
n20/D 1.568 (lit.)
density
1.476 g/mL at 25 °C (lit.)
functional group
bromo, ketone
Quality Level
General description
2′-溴苯乙酮（2-溴苯乙酮）与苯乙炔在手性樟脑磺酰胺的催化下可进行对映选择性加成反应。它在钯催化剂存在下与脂族伯胺反应可得到3-亚甲基异吲哚-1-酮。
Application
2′-溴苯乙酮（2-溴苯乙酮）用于新型非稠合5,5-双环的合成。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.
Gui Lu et al.
Angewandte Chemie (International ed. in English), 42(41), 5057-5058 (2003-11-05)
Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones.
Cho CS, et al.
Synthetic Communications, 32(!2), 1821-1827 (2002)
Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems.
Bonacorso HG, et al.
Synthesis, 2002(08), 1079-1083 (3003)
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