183695
2′-溴苯乙酮
99%
别名:
1-乙酰基-2-溴苯
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关于此项目
线性分子式:
BrC6H4COCH3
化学文摘社编号:
分子量:
199.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-398-1
Beilstein/REAXYS Number:
1931534
MDL number:
Assay:
99%
Form:
liquid
InChI key
PIMNFNXBTGPCIL-UHFFFAOYSA-N
InChI
1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
SMILES string
CC(=O)c1ccccc1Br
assay
99%
form
liquid
refractive index
n20/D 1.568 (lit.)
density
1.476 g/mL at 25 °C (lit.)
functional group
bromo, ketone
Quality Level
Application
2′-溴苯乙酮（2-溴苯乙酮）用于新型非稠合5,5-双环的合成。
General description
2′-溴苯乙酮（2-溴苯乙酮）与苯乙炔在手性樟脑磺酰胺的催化下可进行对映选择性加成反应。它在钯催化剂存在下与脂族伯胺反应可得到3-亚甲基异吲哚-1-酮。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones.
Cho CS, et al.
Synthetic Communications, 32(!2), 1821-1827 (2002)
Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems.
Bonacorso HG, et al.
Synthesis, 2002(08), 1079-1083 (3003)
Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.
Gui Lu et al.
Angewandte Chemie (International ed. in English), 42(41), 5057-5058 (2003-11-05)
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